GCMS calibration table for TCLP method, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\MAR0102\3383.D Vial: 47 Acq On 3 Mar 2002 9:36 am Operator: Sample gc/ms scan 2/4 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 N-Ethylformamide Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.19 1.20 ug/1 199574 1,4-Dichlorobenzene-d4 12.32

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 N-Ethylformamide 73 C3H7NO 000627-45-2 9 2 Butane, 2-methoxy-2-methyl- 102 C6H140 000994-05-8 9 3 Pentane, 3/-methoxy- 102 C6H140 036839-67-5 9 4 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 Abundance C Scan 342 (8.185 min): 3383.D (-) m/ z 73.00 100.00% 73 I ;

5000 43 i- TTrrrsi । rc 87 7.80 8.00 8.20 8.40 8.60 ......... I I I ■ I ,55., ‘I 1,1,., 1 1 1 1 1 1 1 I 1 1 1 1 I 1 1 138 1 . ■ . .11,1 > . . .. 103 . I— m/ z 42.9.5 30.01% m/z-> ___ 10____ 20____ 30 40 50___ 60____ 70.. . 80 90 100 110 Abundance #292: N-Ethylformamide 30 73

5000 ■ i ' ‘ 7.80 ■ i ■ ■ 8.00 8.20 8.40 8.60 44 58 m/z 41.0,5 10.88% .15 m/z-10 DaaaB—aaaUai 20 30 • ■ 1 1 40 1 i ■ ' 50 60 । ' i ■1 ■11 ■ ■' ■ । 70___ 80____ 90 • • • i ■ ■ ■ ■ । ‘ 100 110 Abundance ) .mneh ■ 73

7.80 8.00 8.20 8.40 8.60 5000 m/z 44.95 10.28% 55 87 45 27 33 ■ ■ i ■ 1 1 1 I ■ ■ ■ 1 i ■ 1 ■ ■ i ' ■ i ■ ■ 1 ■ i ■ ■ 1 ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ m/z—> 10___ 20 30 40 50 60 70 80 90___ 100___ 110 Abundance #1793: Pentane, 3-methoxy- ' 1 1 1 1 73 7.80 8.00 8.20 8.40 8.60 m/z 71.00 7.33% 5000 45

.......... 27 33 39, 55 1 i ■ *l* ‘"i > • ■ • r> 1 1 ‘ i ■ ■ ' 1 i ■ ' ■ ■ i ■ ■ ■ ■ i ■ m/z-> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

3383.D GCMS0208.M Mon Mar 25 12:23:23 2002 Page 1

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