GCMS calibration table for TCLP method, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAR0102\3281.D Vial: 41 Acq On 3 Mar 2002 3:39 am Operator: Sample gc/ms scan 2/4 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 N-Ethylformamide Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.19 1.60 ug/1 324759 1,4-Dichlorobenzene-d4 12.32

Hit# Of 5 Tyhtative ID MW MolForm CAS# Qual

1 N-Ethylformamide 73 C3H7NO 000627-45-2 9 2 Silane, tetramethyl- 88 C4H12Si 000075-76-3 9 3 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 4 Butane, 2-methoxy-2-methyl-____ 102 C6H140 000994-05-8 9 Abundance T Scan 343 (8.191 min): 3281 D (-) m/ z 73.00 100.00% 73

5000 43

55 87 103 7.80 8.00 8.20 8.40 8.60 ................................. 37 | I ‘ ■ i ‘ ‘ ■ 1 i ■ • • ■ i 1 ' 1 1 | i'i'i ■ i ' '’i 1 1 67,1 1 ‘T1 — ————— m/z 43.0.5 28.76% m/z-> 10... 20___ 30 40___ 50 60 70 80 90 100 110 120 Abundance #292: N-Ethylformamide 30 73

5000 T 3.I 44 58 7.808.00 8.20 8.40 8.60 m/z 41.0,5 10.56% ...15 1 15B 1 1 i 1 1 m/z->10 20 30 40 50 60 70 80 90 100 110 120 Abundance 73

5000 m/z "TT 7.80 8.00 8.20 8.40 8.60

45 15 53 59 88_______________ **1**‘I‘*I*****1**I****II* ' • i • 1 ' ' i 1 ‘ ' i 1 • ■ ■ i ‘ ■ m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #49423:1,3-Dioxolane, 2-(3-bromo-5,5,5-trichloro-2,2-dimet — PTITTPITTT 73 7,80 8.00 8.20 8.40 8.60 m/z 71.00 “ 7.35% 5000 45 36 i I 55 67. i______________ 109115 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ‘ ■ 1 ' I ' 1 ' ■ । ■ ‘’I । । । । । i'i । 1 ' ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i 1 1 1 ' I ' 1 1 1 1 1 1 1 i ■ ■ ■ ■ i ■ ■ ■ 1 i ■ ■ ■ 1 । ■ ■ ■ ■ । • ■ m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 7.80 8.00 8.20 8.40 8.60

3281.D GCMS0208.M Mon Mar 25 12:17:26 2002 Page 1

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