GCMS calibration table for TCLP analysis, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAR0102\REF2.D Vial: 26 Acq On 2 Mar 2002 10:53 am Operator: Sample gc/ms scan 2/12 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 5 14:04 2002 Quant Results File: GCM

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 27 11:30:15 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.32 152 518636 20.00 ug/1 -0.04 10) Naphthalene-d8 15.96 136 2033255 20.00 ug/1 -0.04 17) Acenaphthene-diO 21.28 164 1078043 20.00 ug/1 -0.04 29) Phenanthrene-diO 25.72 188 1619207 20.00 ug/1 -0.05 38) Chrysene-dl2 33.79 240 1138585 20.00 ug/1 -0.06 44) Perylene-dl2 38.07 264 755064 20.00 ug/1 -0.06

System Monitoring Compounds 37) 2,4-DDD 30.80 235 72869 4.31 ug/mL 0.30 Spiked Amount 5.000 Recovery = 86.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.94 74 63734 3.07 ug/1 # 73 3) bis(2-Chloroethyl)ether 11.71 93 155818 4.57 ug/1 94 4) 1,3-Dichlorobenzene 12.21 146 109217 2.69 ug/1 98 5) 1,4-Dichlorobenzene 12.36 146 114532 2.77 ug/1 99 6) 1,2-Dichlorobenzene 12.88 146 116994 2.98 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 13.20 45 232113 4.50 ug/1 98 8) N-Nitroso-di-n-propylamine 13.58 70 109874 4.51 ug/1 # 85 9) Hexachloroethane 13.73 117 33070 2.00 ug/1 98 11) Nitrobenzene 14.00 77 147084 3.52 ug/1 96 12) 1sophorone 14.65 82 318855 4.51 ug/1 99 13) bis(2-Chloroethoxy)methane 15.33 93 192836 4.38 ug/1 97 14) 1,2,4-Trichlorobenzene 15.84 180 102367 2.94 ug/1 98 15) Naphthalene 16.02 128 403336 3.72 ug/1 99 16) Hexachlorobutadiene 16.56 225 32807 1.58 ug/1 98 18) Hexachlorocyclopentadiene 18.76 237 5708 0.37 ug/1 97 19) 2-Chloronaphthalene 19.52 162 245832 3.82 ug/1 98 20) Dimethylphthalate 20.61 163 349998 4.68 ug/1 99 21) 2,6-Dinitrotoluene 20.83 165 71753 4.23 ug/1 87 22) Ac enapht hylene 20.80 152 387952 4.18 ug/1 99 2 3) Acenaphthene 21.36 153 277280 4.27 ug/1 98 24) 2,4-Dinitrotoluene 22.00 165 93731 4.36 ug/1 # 81 25) Diethylphthalate 22.74 149 344202 4.42 ug/1 97 26) 4-Chlorophenyl-phenylether 22.90 204 141825 4.23 ug/1 96 27) Fluorene 22.88 166 307306 4.34 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.37 77 321553 3.93 ug/L # 87

(#) = qualifier out of range (m) = manual integration REF2.D GCMS0208.M Tue Mar 05 14:07:18 2002 Page 1

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