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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 3, 2001.

NYC-WTC_000087496–000087516

Folder label: “GC/MS Scan 9/20/01

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\1\DATA\OCT0201\LB.D Vial: 2 Acq On : 2 Oct 2001 3:06 pm Operator: 209 GALOS Sample : 9/20 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 2-Hexanol Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T. 6.74 0.69 ug/1 88381 1,4-Dichlorobenzene-d4 11.78 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-HeMnol 102 C6H14O 000626-93-7 83 2 2-P^tanol, 4-methyl- 102 C6H14O 000108-11-2 78 3 2-^tanol 74 C4H10O 000078-92-2 50 4 2-^exanol, (S) - 102 C6H14O 052019-78-0 43 ^bundarfce Scan 185 (6.736 min): LB.D(-) m/z 44795 100.00% 40 (1

5000

69 TT-p-r-r-t-p-r TT-r-'-n-rT- 41 6.40 6.60 6.80 7.00 co 56 I 84 87 I' " ' I " " I " " I " " I I........ ... ............................ . ......................................................... m/z 69.10 15.66% m/z-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ^bundance #63584: 2-Hexanol 4b

5000 -i-|. rr-p-i-r-.-| 6.40 6.80 7.00 41.05 13.97% 69 19 27,31 4^1 56 I"" 111111111' I' 1111111111H111 n I . ........... . Tife-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #63546: 2-Pentanol, 4-methyl- 40 6.40 6.60 6.80 7.00 5000 m/z 43.00 9.79%

27 69 19 I 3,1 42 57 8487 I' > " I' •' 11 ■' ■' I • I " 11" ■ I i>"|""|llii| I................. TiZz-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 '\bundance #62568:2-Butanol 40 6.40 6.60 6.80 7.00 m/z 43.95 8.47%

5000

59 27 .... : . 72 prt-r I'''' I'''' I'''' I ' ' I ' ' ' ' I ' ' ' ' I 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 6.40 6.60 6.80 7.00

LB.D NP091101.M Wed Oct 03 10:09:50 2001 Page 4

NYC-WTC_000087505

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