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GCMS analysis results for sample AE06853, April 2002

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Laboratory report documenting GCMS analysis of sample AE06853 conducted on April 11, 2002, identifying unknown compounds.

NYC-WTC_000060649–000060663

Folder label: “GCMS X 3/22/02 A 4/7/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\040502\6853.D Vial: 46 Acq On 7 Apr 2002 8:44 am Operator: Bohlk Sample SAMPLE 6853 3/22/02. Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\MSDCHEM\l\5973N\5080402.M (RTE Integrator) Title Quantitation For Method 508gcscan Library C:\DATABASE\WILEY7N.L ********************************************************************* Peale Number 2 2-(2,2-dimethylcyclopropyl) ... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

35.74 0.54 ug/L 191918 Perylene-dl2 34.11

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-(2,2-dimethylcyclopropyl)-3-me. .. 164 C11H16O 117873-34-4 14 2 1,3,3-trimethyl-cis,exo-tricyclo... 164 C11H16O 117873-24-2 14 3 (-)-Caryophyllene oxide $$ (-)-5... 220 C15H24O 001139-30-6 11 4 7-Pentadecyne 208 C15H28 _______ 022089-89-0 11 Abundance Scan 5558 (35.736 min): 6853.D (-) m/z 43.10 100.00% 43

93 67 215 5000 133

165 191 248 355 l«,I,Dill J. m/z--> Abundance 0 50 I 100 150 200 II 250 X 300 #65244: 2-{2,2-dimethyicyclopropyl)-3-methyl-2-cyclopenten... 350 35.40 35.60 35.80 36.00 m/z 57.20 84.32%

93

5000 35.40 35.60 35.80 36.00 121 149 m/z 55.05 74.59%

m/z-> 0 4-^ 50 100 150 200 250 300 350 Abundance

uuJm #65243; 1.3,3-trimethyl-cis,exo-tricyclot3.3.0.0{2,4)]octa... 93

35.40 35.60 35.80 36.00 552 ■m/z 93710 65.20%

121 149

0 nn/z-> 50 100 150 200 250 300 350 Abundance 43 #145060: (-)-Caryophyllene oxide S$ (-)-5-Oxatricyclo[8.2.... 4UL 35.40 35.60 35.80 36.00 m/z 95710 62.49%

5000 79 109

m/z-> 0 I 50 100 150 200 250 300 350 35.40 35.60 35.80 36.00

6853.D 5080402.M Wed Apr 10 08:00:30 2002 Page 4

NYC-WTC_000060657

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NYC-WTC_000060657Source: NYC Law Department, mirrored locally

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