GCMS surrogate recovery, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\041002\7116.D Vial: 23 Acg On : 11 Apr 2002 8:04 am Operator: Bohlk Sample : SAMPLE 7116 3/27/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l\5973N\5080402BB.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L *******★***★★**★**★*★★★*★*★★★**★***★★**★★*******★★***★****★*★*★★*★*** Peak Number 3 dl-2-Ethylhexyl chloroforma... Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

30.47 1.89 ug/L 237516 Chrysene-dl2 30.14

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 dl-2-Ethylhexyl chloroformate $$... 192 C9H17C1O2 024468-13-1 80 2 1-Octene (CAS) $$ Caprylene $$ n... 112 C8H16 000111-66-0 58 3 2-Cyclopenten-l-one, 2-hydroxy-3... 112 C6H8O2 000080-71-7 43 4 2-Cyclopenten-l-one, 2-hydroxy-3... 112 C6H8O2 000080-71-7 43 Abundance Scan 4661 (30.465 min): 7116.D (-) m/z 57.10 100.00%

i 57 112 70

5000 43 83

239 256 30.20 30.40 30.60 30.80 129 0( hl il, I I .1 m/z 112.20 81.85% ’ I ' r• 1 I Tl/z-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #102311: dl-2-Ethylhexyl chloroformate $S 2-Ethylhexyl chi... 57 112 70

5000 43 83 30.20 30.40 30.60 30.80 m/z 70.20 70.58% 97 129 149 192 0 X ‘I .................. ..... -p-m- m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #13725: 1-Octene (CAS) SS Caprylene $S n-l-Octene SS .alph... 1 2

70 K I ' ' ' ' I 30.20 30.40 30.60 30.80 Av.. m/z 71.10 68.66% WHill

56

42 I y 0 ■n/z-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #13117: 2-Cyclopenten-1-one, 2-hydroxy-3-methyl- (CAS) $S ... ..V....... 1 2 30.20 30.40 30.60 30.80 m/z 43.10 41.17%

lililil 55 69 41 83

m/z-> 0 40 60 80 97 I 131 m-T-j- 100 120 140 160 180 200 220 240 260 ■R L 30.20 30.40 30.60 30.80

7116.D 5080402BB.M Mon Apr 15 18:21:46 2002 Page 5

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