GCMS reference standard results, sample AE05515, April 2002

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Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\APR0102\REFl.D Vial: 4 Acq On 1 Apr 2002 2:11 pm Operator: Sample gc/ms scan 3/11 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 4 12:24 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 580314 20.00 ug/1 -0.10 10) Naphthalene-d8 15.88 136 2170683 20.00 ug/1 -0.11 17) Acenaphthene-dlO 21.20 164 1219857 20.00 ug/1 -0.11 29) Phenanthrene-dlO 25.64 188 1761616 20.00 ug/1 -0.12 38) Chrysene-dl2 33.70 240 982717 20.00 ug/1 -0.14 44) Perylene-dl2 37.94 264 554960 20.00 ug/1 -0.18

System Monitoring Compounds 37) 2,4-DDD 30.71 235 82657 4.68 ug/mL 0.21 Spiked Amount 5.000 Recovery = 93.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.89 74 74280 3.77 ug/1 # 71 3) bis(2-Chloroethyl)ether 11.64 93 188770 5.95 ug/1 89 4) 1,3-Dichlorobenzene 12.15 146 165394 -5.05 ug/1 100 5) 1,4-Dichlorobenzene 12.29 146 172353 5.25 ug/1 99 .6) 1,2-Dichlorobenzene 12.81 146 168417 5.50 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 13.13 45 266266 5.97 ug/1 99 8) N-Nitroso-di-n-propylamine 13.52 70 128035 6.21 ug/1 # 83 9) Hexachloroethane 13.66 117 54732 4.46 ug/1 90 11) Nitrobenzene 13.93 77 174870 5.89 ug/1 93 12) Isophorone 14.58 82 380468 6.76 ug/1 98 13) bis(2-Chloroethoxy)methane 15.26 93 235887 6.40 ug/1 99 14) 1,2,4-Trichlorobenzene 15.77 180 151439 5.94 ug/1 96 15) Naphthalene 15.94 128 522863 6.52 ug/1 99 16) Hexachlorobutadiene 16.49 225 63074 4.97 ug/1 . 97 18) Hexachlorocyclopentadiene .18.68 237 11542 1.40 ug/1 95 19) 2-Chloronaphthalene 19.45 162 333819 6.37 ug/1 96 20) Dimethylphthalate 20.54 163 459184 7.48 ug/1 99 21) 2,6-Dinitrotoluene 20.75 165 94769 6.36 ug/1 # 84 22) Acenaphthylene 20.72 152 513516 6.86 ug/1 99 23) Acenaphthene 21.28 153 363977 6.96 ug/1 99 24) 2,4-Dinitrotoluene 21.92 165 121605 6.10 ug/1 # 74 25) Diethylphthalate 22.67 149 447381 7.51 ug/1 94 .26) 4-Chlorophenyl-phenylether 22.82 204 200255 7.85 ug/1 92 27) Fluorene 22.81 166 409040 7.39 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.29 77 379830 5.95 ug/L #. 83

(#) = qualifier out of range (m) = manual integration REFl.D GCMS0403.M Thu Apr 04 12:28:13 2002 Page 1

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