GCMS calibration data review for Method 508, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\0 2 2 2 0 2\CAL4 0.D Vial: 17 • Acq On : 23 Feb 2002 2:06 am Operator: McLean Sample : 1/14/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Feb 25 19:18:49 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.58 150 1066235 20.00 ug/L 0.00 10) Naphthalene-d8 13.06 136 2386491 20.00 ug/L 0.00 17) Acenaphthene-diO 18.17 164 1235675 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.53 188 1988402 20.00 ug/L 0.00 38) Chrysene-dl2 30.36 240 1775993 20.00 ug/L 0.00 44) Perylene-dl2 34.22 264 1280680 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.46 235 19035 0.60 ug/L 0.00 Spiked Amount 5.000 Recovery = 12.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.57 74 1135875 35.22 ug/L 100 3) bis(2-chloroethyl) ether 9.03 93 1742800 34.52 ug/L 99 4) 1,3 - Dichlorobenze 9.42 146 1694144 35.54 ug/L 99 5) 1,4 - Dichlorobenzene 9.62 146 1697522 35.84 ug/L 98 6) 1,2 - Dichlorobenzene 10.01 146 1570066 35.80 ug/L 100 7) 2,2 ' - oxybis (l-Chloropr 10.48 45 4108769 33.66 ug/L 98 8) N-Nitroso-di-n-propylamine 10.83 70 1404347 36.27 ug/L 98 9) Hexachloroethane 10.89 117 677994 35.40 ug/L 99 11) Nitrobenzene 11.16 77 2095343 37.67 ug/L 100 12) Isophorone 11.88 82 3791275 37.36 ug/L 100 13) bis(2-Chloroethoxy) methan 12.61 93 2301070 37.42 ug/L 100 14) 1,2,4-Trichlorobenzene 12.94 180 1314138 38.72 ug/L 99 15) Naphthalene 13.13 128 4729509 37.68 ug/L 99 16) Hexachlorobutadiene 13.57 225 749549 39.77 ug/L 98 18) Hexachlorocyclopentadiene 15.64 237 487177 40.31 ug/L 97 19) 2-chloronaphthalene 16.55 162 2773941 39.28 ug/L 99 20) Dimethylphthalate 17.65 163 3319757 39.41 ug/L 99 21) 2,6-Dinitrotoluene 17.76 165 680040 39.56 ug/L 98 22) Acenaphthylene 17.73 152 3817200 39.32 ug/L 100 23) Acenaphthene 18.28 153 2603647 38.60 ug/L 99 24) 2,4-Dinitrotoluene 18.91 165 1002562 40.62 ug/L 97 25) Diethylphthalate 19.79 149 2911206 40.34 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.94 204 1486249 39.61 ug/L 95 27) Fluorene 19.81 166 3020329 39.30 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.40 77 4181511 37.93 ug/L 99 30) N-Nitrosodiphenylamine 20.33 169 2060053 38.82 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.36 248 858871 40.91 ug/L 95 32) Hexachlorobenzene 21.40 284 876098 40.54 ug/L 96 33) Phenanthrene 22.61 178 4449117 38.60 ug/L 99 34) Anthracene 22.76 178 4272643 38.62 ug/L 100 35) Di-n-butylphthalate 24.70 149 5361578 40.25 ug/L 100 36) Fluoranthene 26.11 202 5236789 39.49 ug/L 99 39) Pyrene 26.74 202 5364036 37.16 ug/L 99 40) Butylbenzylphthalate 29.10 149 2461623 39.82 ug/L 95 41) Benzo (a) antracene 30.33 228 4466870 38.34 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.96 149 3215033 39.92 ug/L 98 43) Chrysene 30.44 228 4259685 37.50 ug/L 100 45) Di-n-Octylphthalate 32.80 149 5483540 41.76 ug/L 98 46) Benzo (b) fluoranthene 33.29 252 4231980 39.50 ug/L 100

(#) = qualifier out of range (m) = manual integration CAL40.D 5080202.M Wed Feb 27 06:27:04 2002 Page 1

NYC-WTC_000052361