GCMS calibration results for sample AE01641, Mar 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\022602\CAL40MIX.D Vial: 15 ACq On : 26 Feb 2002 10:21 pm Operator: McLean Sample : 1/24 Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Feb 28 11:31:13 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.60 150 2151365 20.00 ug/L 0.02 10) Naphthalene-d8 13.08 136 4712970 20.00 ug/L 0.02 17) Acenaphthene-dlO 18.19 164 2510222 20.00 ug/L 0.02 29) Phenanthrene-dlO 22.55 188 4162333 20.00 ug/L 0.02 38) Chrysene-dl2 30.39 240 3412790 20.00 ug/L 0.03 44) Perylene-dl2 34.24 264 2446178 20.00 ug/L 0.02

System Monitoring Compounds 37) 2,4-ddd surr 27.48 235 41116 0.62 ug/L 0.01 Spiked Amount 5.000 Recovery = 12.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.60 74 2374615 36.50 ug/L 100 3) bis(2-chloroethyl) ether 9.06 93 3396729 33.35 ug/L 97 4) 1,3 - Dichlorobenze 9.43 146 3363966 34.98 ug/L 99 5) 1,4 - Dichlorobenzene 9.64 146 3341080 34.96 ug/L 99 6) 1,2 - Dichlorobenzene 10.02 146 3020876 34.14 ug/L 98 7) 2,2 1 - oxybis (l-Chloropr 10.49 45 7787650 31. 61 ug/L 98 8) N-Nitroso-di-n-propylamine 10.86 70 2507498 32.09 ug/L 98 9) Hexachloroethane 10.90 117 1258245 32.56 ug/L 94 11) Nitrobenzene 11.19 77 4168917 37.95 ug/L 98 12) Isophorone 11.91 82 7784463 38.85 ug/L 99 13) bis(2-Chloroethoxy) methan 12.64 93 4508921 37.12 ug/L 99 14) 1,2,4-Trichlorobenzene 12.95 180 2569832 38.34 ug/L 100 15) Naphthalene 13.14 128 9191823 37.09 ug/L 100 16) Hexachlorobutadiene 13.58 225 1493696 40.13 ug/L 96 18) Hexachlorocyclopentadiene 15.65 237 1057081 43.06 ug/L 99 19) 2-chloronaphthalene 16.57 162 5475116 38.17 ug/L 98 20) Dimethylphthalate 17.69 163 6833448 39.93 ug/L 100 21) 2,6-Dinitrotoluene 17.79 165 1457343 41.73 ug/L 96 22) Acenaphthylene 17.75 152 7567738 38.38 ug/L 100 23) Acenaphthene 18.30 153 5143503 37.54 ug/L 99 24) 2,4-Dinitrotoluene 18.96 165 2119246 42.27 ug/L 96 25) Diethylphthalate 19.81 149 5660845 38.61 ug/L 100 26) 4-Chlorophenyl-phenyl ethe 19.96 204 3012980 39.52 ug/L 98 27) Fluorene 19.83 166 5819371 37.27 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.42 77 9026793 40.31 ug/L 100 30) N-Nitrosodiphenylamine 20.35 169 3983428 35.86 ug/L 100 31) 4-Bromophenyl-phenyl ether 21.38 248 1696635 38.60 ug/L 97 32) Hexachlorobenzene 21.42 284 1781622 39.39 ug/L 98 33) Phenanthrene 22.63 178 8807812 36.50 ug/L 100 34) Anthracene 22.79 178 8383415 36.20 ug/L 100 35) Di-n-butylphthalate 24.71 149 10587316 37.97 ug/L 99 36) Fluoranthene 26.13 202 10566409 38.06 ug/L 99 39) Pyrene 26.77 202 11031566 39.78 ug/L 97 40) Butylbenzylphthalate 29.12 149 4924885 41.45 ug/L 96 41) Benzo (a) antracene 30.35 228 8935251 39.91 ug/L 100 42) Bis (2-ethylhexyl) phthala 30.97 149 6432032 41.56 ug/L 99 43) Chrysene 30.47 228 8437403 38.66 ug/L 99 45) Di-n-Octylphthalate 32.82 149 10686586 42.60 ug/L 98 46) Benzo (b) fluoranthene 33.32 252 8430329 41.19 ug/L 99

(#) = qualifier out of range (m) = manual integration CAL40MIX.D 5080202.M Thu Feb 28.11:31:24 2002 Page 1

NYC-WTC_000052428