GCMS calibration results for sample AE02457, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) J. . ♦ 5ata File : C:\MSDCHEM\1\DATA\022702\ .D Vial: 2 A8q Oh : 27 Feb 2002 6:52 am Operator: McLean Sample : CAL 40 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 01 08:45:38 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\1\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.59 150 1894935 20.00 ug/L 0.00 10) Naphthalene-d8 13.07 136 4192551 20.00 ug/L 0.00 17) Acenaphthene-diO 18.18 164 2200043 20.00 ug/L 0.00 29) Phenanthrene-d10 22.54 188 3564094 20.00 ug/L 0.00 38) Chrysene-dl2 30.39 240 3079791 20.00 ug/L 0.03 44) Perylene-d12 34.24 264 2193404 20.00 ug/L 0.02

System Monitoring Compounds 37) 2,4-ddd surr 27.47 235 36382 0.64 ug/L 0.00 Spiked Amount 5.000 Recovery 12.80% =2

Target Compounds 10 52 Qvalue 2) N-nitroso-dimethyl amine 3.59 74 2051521 35.80 ug/L 100 3) bis(2-chloroethyl) ether 9.05 93 3046129 33.95 ug/L 99 4) 1,3 - Dichlorobenze 9.42 146 2989341 35.29 ug/L 100 5) 1,4 - Dichlorobenzene 9.64 146 2938142 34.90 ug/L 100 6) 1,2 - Dichlorobenzene 10.02 146 2690162 34.51 ug/L 99 7) 2,2 ' - oxybis (l-Chloropr 10.49 45 7055315 32.52 ug/L 99 8) N-Nitroso-di-n-propylamine 10.85 70 2217426 32.22 ug/L 100 9) Hexachloroethane 10.90 117 1162504 34.16 ug/L 98 11) Nitrobenzene 11.18 77 3720222 38.07 ug/L 99 12) Isophorone 11.90 82 6685837 37.51 ug/L 100 13) bis(2-Chloroethoxy) methan 12.64 93 3939620 36.46 ug/L 99 14) 1,2,4-Trichlorobenzene 12.95 180 2328074 39.04 ug/L 99 15) Naphthalene 13.14 128 8186140 37.13 ug/L 100 16) Hexachlorobutadiene 13.58 225 1343218 40.57 ug/L 100 18) Hexachlorocyclopentadiene 15.65 237 900493 41.85 ug/L 97 19) 2-chloronaphthalene 16.57 162 4837308 38.47 ug/L 99 20) Dimethylphthalate 17.68 163 5954773 39.71 ug/L 99 21) 2,6-Dinitrotoluene 17.79 165 1268654 41.45 ug/L 97 22) Acenaphthylene 17.75 152 6603689 38.21 ug/L 100 23) Acenaphthene 18.30 153 4532795 37.75 ug/L 100 24) 2,4-Dinitrotoluene 18.95 165 1856700 42.26 ug/L 99 25) Diethylphthalate 19.81 149 5105616 39.74 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.96 204 2622288 39.25 ug/L 99 27) Fluorene 19.83 166 5151320 37.64 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.42 77 7860764 40.05 ug/L 99 30) N-Nitrosodiphenylamine 20.35 169 3461486 36.39 ug/L 100 31) 4-Bromophenyl-phenyl ether 21.38 248 1476721 39.24 ug/L 97 32) Hexachlorobenzene 21.42 284 1561769 40.32 ug/L 96 33) Phenanthrene 22.63 178 7759090 37.55 ug/L 99 34) Anthracene 22.78 178 7348824 37.05 ug/L 100 35) Di-n-butylphthalate 24.71 14 9 9389963 39.33 ug/L 100 36) Fluoranthene 26.13 202 9318013 39.20 ug/L 99 39) Pyrene 26.76 202 9684171 38.69 ug/L 97 40) Butylbenzylphthalate 2 9.11 149 4394226 40.99 ug/L 94 41) Benzo (a) antracene 3 0.35 228 7952048 39.35 ug/L 100 42) Bis (2-ethylhexyl) phthala 30.97 149 5772532 41.33 ug/L 99 43) Chrysene 3 0.4 7 228 7617894 38.68 ug/L 99 45) Di-n-Octylphthalate 32.82 149 9677936 43.03 ug/L 98 46) Benzo (b) fluoranthene 33.31 252 7464640 40.68 ug/L 99

(#) = qualifier out of range (m) = manual integration CAL40X.D 5080202.M Fri Mar 01 08:45:55 2002 Page 1

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