GCMS calibration data for Method 508, Mar 11-14 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\MSDCHEM\1\DATA\031102\ 0311.D Vial: 6 Acq On : 11 Mar 2002 3:45 pm Operator: McLean Sample : C40 Inst : Instrumen Mise Multipir: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 14 12:23:39 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Wed Mar 13 06:26:00 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.56 150 2166534 20.00 ug/L 0.00 10) Naphthalene-d8 13.04 136 5054222 20.00 ug/L 0.02 17) Acenaphthene-diO 18.15 164 2742586 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.51 188 4504654 20.00 ug/L 0.02 38) Chrysene-dl2 30.34 240 3672392 20.00 ug/L 0.02 44) Perylene-dl2 34.20 264 2192526 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 34938 5.33 ug/L 0.00 Spiked Amount 5.000 Recovery = 106.60%

Target Compounds 2% / Qvalue 2) N-nitroso-dimethyl amine 3.57 74 1896090 38.97 ug/L 100 3) bis(2-chloroethyl) ether 9.02 93 2862868 37.33 ug/L 97 4) 1,3 - Dichlorobenze 9.39 146 2858070 37.68 ug/L 99 5) 1,4 - Dichlorobenzene 9.61 146 2831532 37.43 ug/L 99 6) 1,2 - Dichlorobenzene 9.99 146 2593981 37.04 ug/L 100 7) 2,2 ' - oxybis (l-Chloropr 10.45 45 6594742 37.75 ug/L 98 8) N-Nitroso-di-n-propylamine 10.81 70 2235429 40.54 ug/L 100 9) Hexachloroethane 10.87 117 1102903 38.81 ug/L 98 11) Nitrobenzene 11.14 77 3489962 38.34 ug/L 99 12) Isophorone 11.87 82 6467211 38.61 ug/L 99 13) bis(2-Chloroethoxy) methan 12.59 93 3863909 38.33 ug/L 99 14) 1,2,4-Trichlorobenzene 12.92 180 2231996 38.57 ug/L 100 15) Naphthalene 13.11 128 8024243 38.20 ug/L 99 16) Hexachlorobutadiene 13.54 225 1256451 38.83 ug/L 98 18) Hexachlorocyclopentadiene 15.61 237 1120243 46.39 ug/L 98 19) 2-chloronaphthalene 16.54 162 4827757 38.56 ug/L 100 20) Dimethylphthalate 17.64 163 5913377 39.57 ug/L 99 21) 2,6-Dinitrotoluene 17.74 165 1272705 40.01 ug/L 98 22) Acenaphthylene 17.72 152 6734386 38.77 ug/L 99 23) Acenaphthene 18.26 153 4561365 38.63 ug/L 99 24) 2,4-Dinitrotoluene 18.90 165 1851686 40.66 ug/L 98 25) Diethylphthalate 19.77 149 5082297 39.52 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.92 204 2650248 38.67 ug/L 99 27) Fluorene 19.79 166 5297241 38.05 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.38 77 7260465 38.28 ug/L 98 30) N-Nitrosodiphenylamine 20.31 169 3700726 38.22 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.34 248 1520906 38.25 ug/L 97 32) Hexachlorobenzene 21.37 284 1578895 37.65 ug/L 98 33) Phenanthrene 22.59 178 7916833 37.95 ug/L 99 3 4) Anthracene 22.74 178 7842167 37.88 ug/L 100 35) Di-n-butylphthalate 24.67 149 9318233 38.97 ug/L 100 36) Fluoranthene 26.09 202 9160724 38.64 ug/L 99 39) Pyrene 26.72 202 9420540 37.11 ug/L 97 40) Butylbenzylphthalate 29.07 149 4168565 38.35 ug/L 95 41) Benzo (a) antracene 30.31 228 7526948 39.05 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.93 149 5462524 38.01 ug/L 99 43) Chrysene 30.42 228 6920645 37.79 ug/L 99 45) Di-n-Octylphthalate 32.77 149 8969226 38.09 ug/L 100 46) Benzo (b) fluoranthene 33.26 252 6081407 39.36 ug/L 99

(#) = qualifier out of range (m) = manual integration C40A0311.D 5080302.M Thu Mar 14 12:24:10 2002 Page 1

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