GCMS method 508 calibration data sheet, Feb 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\MSDCHEM\1\DATA\022102\CAL5.D Vial: 7 Acq On : 21 Feb 2002 8:14 pm Operator: McLean Sample : 80 MIX Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Feb 27 06:06:28 2002 <Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.60 150 1320957 20.00 ug/L 0.02 10) Naphthalene-d8 13.08 136 3105825 20.00 ug/L 0.02 17) Acenaphthene-dlO 18.19 164 1702720 20.00 ug/L 0.02 29) Phenanthrene-dlO 22.55 188 2794256 20.00 ug/L 0.02 38) Chrysene-dl2 30.40 240 2201548 20.00 ug/L 0.04 44) Perylene-dl2 34.25 264 1610425 20.00 ug/L 0.03

System Monitoring Compounds 37) 2,4-ddd surr 27.47 235 28102 0.63 ug/L 0.00 Spiked Amount 5.000 Recovery = 12.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.61 74 3077987 77.04 ug/L 100 3) bis(2-chloroethyl) ether 9.07 93 4262750 68.16 ug/L 96 4) 1,3 - Dichlorobenze 9.43 146 4149730 70.27 ug/L 100 5) 1,4 - Dichlorobenzene 9.65 146 4046755 68.96 ug/L 99 6) 1,2 - Dichlorobenzene 10.03 146 3707573 68.24 ug/L 98 7) 2,2 ' - oxybis (l-Chloropr 10.50 45 10294978 68.07 ug/L 98 8) N-Nitroso-di-n-propylamine 10.88 70 2871488 59.85 ug/L 100 9) Hexachloroethane 10.91 117 1420570 59.88 ug/L 99 11) Nitrobenzene 11.20 77 5424180 74.92 ug/L 99 12) Isophorone 11.94 82 10377620 78.58 ug/L 99 13) bis(2-Chloroethoxy) methan 12.66 93 5884659 73.52 ug/L 99 14) 1,2,4-Trichlorobenzene 12.96 180 3146095 71.22 ug/L 99 15) Naphthalene 13.16 128 11398801 69.79 ug/L 100 16) Hexachlorobutadiene 13.59 225 1732576 70.64 ug/L 99 18) Hexachlorocyclopentadiene 15.66 237 1527208 91.71 ug/L 99 19) 2-chloronaphthalene 16.58 162 6811459 70.00 ug/L 99 20) Dimethylphthalate 17.72 163 8591840 74.02 ug/L 99 21) 2,6-Dinitrotoluene 17.71 165 93536 3.95 ug/L 49 22) Acenaphthylene 17.77 152 9430524 70.50 ug/L 100 23) Acenaphthene 18.31 153 6502208 69.96 ug/L 99 24) 2,4-Dinitrotoluene 18.99 165 2717767 79.92 ug/L 95 25) Diethylphthalate 19.84 149 6529475 65.66 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.97 204 3642620 70.45 ug/L 98 27) Fluorene 19.85 166 6971433 65.82 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.44 77 11351476 74.73 ug/L 100 30) N-Nitrosodiphenylamine 20.38 169 5145883 69.00 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.40 248 2016458 68.34 ug/L 96 32) Hexachlorobenzene 21.43 284 2109376 69.46 ug/L 96 33) Phenanthrene 22.65 178 11057251 68.26 ug/L 99 34) Anthracene 22.80 178 10769498 69.26 ug/L 100 35) Di-n-butylphthalate 24.73 149 13041886 69.67 ug/L 100 36) Fluoranthene 26.15 202 13226627 70.97 ug/L 97 39) Pyrene 26.79 202 13541533 75.69 ug/L 99 40) Butylbenzylphthalate 29.13 149 6210727 81.04 ug/L 94 41) Benzo (a) antracene 30.37 228 11367783 78.70 ug/L 98 42) Bis (2-ethylhexyl) phthala 30.98 149 7880757 78.94 ug/L 99 43) Chrysene 30.49 228 10408627 73.93 ug/L 99 45) Di-n-Octylphthalate 32.83 149 13417529 81.25 ug/L 98 46) Benzo (b) fluoranthene 33.33 252 10468819 77.70 ug/L 100

(#) = qualifier out of range (m) = manual integration CAL5.D 5080202.M Wed Feb 27 06:06:33 2002 Page 1

NYC-WTC_000052345