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GCMS analysis results for sample AE00832, Feb 4 2002

Machine-extracted title · confidence 90%

Laboratory report showing GCMS analysis of sample AE00832 including surrogate recovery and unknown compounds.

NYC-WTC_000052147–000052166

Folder label: “GCMS X 1/11/02 A 1/31/02

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Scanned page image, NYC-WTC_000052161
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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN31\00832.D Vial: 5 Acq On : 31 Jan 2002 1:52 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 31, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l..-\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************* ** ** * * ****** Peak Number 9 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

22.28 0.19 ug/L 166936 Phenanthrene-d10 22.65

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 59 3 6-Methoxy-2,4-dihydroxy-l,5-naph... 192 C9H8N2O3 000000-00-0 50 4 Pyrazine, tetraethyl- (CAS) $$ t... 192 C12H20N2 038325-19-8 50 Abundance Scan 1656 (22.280 min): 00832.D (-) m/z 192.10 100.00% 192

5000

96 146 160 । 22.00 22.20 22.40 22.60 O 70 82 118I | I i-i i | i - +— " I 1 ' rrr* ' ' I | r ui । i I I i | i . I I । 1'1 Tr.Il'i । i i n | i n 42 it m/z 191.10 18.00% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588: 4-METHOXY-BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

5000 108 . A 22.00 22.20 22 40 22.60 146 175 m/ z 96.10 15.34%

0 I'|1।11|‘11 t| n11 I■'■||..|i|u ti|r...|i. ITIVIITTTIIII . । ‘ i Tip-n , j ‘ r tT m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #88409: N-perdeuteriobenzylideneaniline 192 TBmTmrmg 22.00 22.20 22 40 22.60 5000 82 m/z 193.10 14.78%

54 110 30 94 160 0 ! , I I | I I U ITT T ‘ ITTTTTTT - mmPTTRTTTTTT+ m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102277:6-Methoxy-2,4-dihydroxy-1,5-naphthyridine ---------- 192 22.00 22.20 22 40 22.60 m/z 146.10 13.49%

5000 52 80 149 163 108 19 122 134 0 TTmB‘100171 I rii"' 'i1'" e iu ।"rn L "I ’ 1 H | ! I 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 11 ■ f > I > ■ i ■ > >' IITT A 1 TP 22.00 22.20 22.40 22.60

00832.D SCAN508.M Fri Feb 01 09:18:52 2002 Page 11

NYC-WTC_000052161

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NYC-WTC_000052161Source: NYC Law Department, mirrored locally

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