GCMS results for sample AE00700, Feb 13 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C : \MSDCHEM\1\5973N\02FEB01\00700 . D Vial: 7 • Acq On : 1 Feb 2002 7:42 pm Operator: Sample : 508 scan Inst : Instrumen Mise 2002 : February 1, Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 5.93 0.35 ug/L 133137 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX -3-EN-YL) PROPANOL $$... 174 C8H14O4 015745-87-6 33 2 Acetic acid, 3- [1,3] dioxolan-2-y. . . 174 C8H14O4 000000-00-0 33 3 1,3-Dioxolane, 2-(3-bromo-5,5,5-... 352 C10H16BrC13O2 000000-00-0 23 4 1-Propenyl-thiol________________ 74 C3H6S 000925-89-3 9 Abundance 7 Scan 224 (5.931 min): 00700.D (-) m/z 73.10 100.00% 7b

5000

43 ■ ■ i 1 < ‘ • i ■

5.60 5.80 6.00 6.20 l 87 103 0 . ।.. ■. । > . . . | I! . , I’ ’ ’I I I I ’I’ I" i ■ ■ ■' i ■' ■ ■ i ■ I ■' ■ ■ i' ■ ■11 ■ ■ ■' i i ■ ■ ■ ■ i m/z 43.10 23.82% n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance i#36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 7(3

5000 ■ i ■ • ■ • i ■ ■ > ■ i 5.60 5.80 6.00 6.20 43 m/z 41.10 11.44% 27 113 87 0 IPP’4 ■ । •55 > > ■ । • ■ > • । ■ H 11 TIT i''' ■ i ■' ■ ■ i' •'' r ' ■' r ''' i 174 ■l•>■•l> n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-{ 1,3]dioxolan-2-ylpropyl ester 73 L======A 5,60 5.80 6.00 6.20 5000 m/z 45.10 11.06% 43 27 55 .1 + T87 113 174 0 I 1 1 ''' i ' 1 ' 1 i'1 1 1 TTUIITT ’T 111" i ■ " • i " ■ ■ i' ■ ’ ■ i ■ ■' • i ■ I'''' I' n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #299410: 1,3-Dioxolane, 2-(3-bromo-5,5>5-trichloro-2,2-dim... 73 5.60 5.80 6.00 6.20 m/z 71.00 6.28%

5000

45 36 , । 55 m/z—> O-mTTT 1 । reo . ml ’! . 109 20 30 40 50 I60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

>0700.D SCAN508.M Mon Feb 04 08:40:51 2002 Page 7

NYC-WTC_000051816