GCMS analysis results for sample AD31639, Jan 28 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN17\31639.D Vial: 2 Acq On : 17 Jan 2002 3:39 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 17, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 2 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 5.89 5.05 ug/L 1639030 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 33 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 33 3 Silane, tetramethyl- 88 C4H12Si 000075-76-3 9 4 Silane, tetramethyl- (CAS) $$ Te... 88 C4H12Si 000075-76-3 9 Abundance Scan 220 (5.885 min): 31639.D (-) m/z 73.10 100.00% 73

5000 43 1 1 i ■ 1 1 ‘ i ■ • ■ ■ 5.60 5.80 6.00 6.20 0- 111'|,1.1 111 ’ • l • “ ‘ I 55 it FIlTT 'l'i 'i 11 i-i'i'i'i ,i. 11 ■ rri 87 111111103 i'i 11111 > 1111111111111111 111,1111 > 111 > 111 ■ m/z 43.10 24.57% n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5000 Tit i • ‘ TIa TTTE' 5.60 5.80 6.00 6.20 43 m/z 45.10 9.26% 27 113 55 , 87 174 0- 111111111"111 Tppm +p IBAyunaayaann 11 ■ ■ । i ■ ■1 ■ i1 ■" i" " । । ■ i ■ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73 111141’** ■ i1 * * » । * * 5.60 5.80 6.00 6.20 5000 m/z 41.10 8.91% 43 27 55 , 1 TTu 87 113 174 0 11'''' I' ।1111"' l'1 ——m1—0uuOBtuug iz—> 10 20 30 40 50 60 70 80 100 110 120 130 140 150 160 170 180 Abundance #4814: Silane, tetramethyl- I*** 73 5.60 5.80 6.00 6.20 m/z 71.10 6.44%

50001

45 15 88 53 0-'i 111 i'i 111,111111111 l'i 11 । u 11 f • • i ■ ■ ■11 “ ‘ ■ i' • i ■ “ ■ i‘ “ ■ i ■ “ ■ i “ ■ ■ i ■ ■ •11 ■1" i • ■ “ i' miz—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

31639.D SCAN508.M Tue Jan 22 08:37:08 2002 Page 4

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