GCMS analysis results for sample AE00320, Jan 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN08\320.D Vial: 5 Acq On : 8 Jan 2002 8:47 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 1-Hexene, 4,5-dimethyl- $$ ... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

5.01 0.17 ug/L 57295 1,4-Dichlorobenzene-d4 . 9.72

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 1-Hexene, 4,5-dimethyl- $$ 4,5-D... 112 C8H16 016106-59-5 2 Butanoic acid, 2-propenyl ester 128 C7H12O2 002051-78-7 3 Butane, 2,2-dimethyl- (CAS) $$ 2... 86 C6H14 000075-83-2 9 4 methyl 2-oxo-3-methylbutanoate 130 C6H10O3 000000-00-0 9 Abundance Scan 143 (5.006 min): 320. D (-) m/z 43.10 100.00% 43 71

5000 59

53 Aw N . / yw MAj., n/z-> O' I 1 1 ' 1 i 1 20 30 40 lqll.. il . 50 60 70 80 90 84................................................

100 110 120 130 4.60 m/z 4.80 71.05 5.00 5.20 5.40 99.46% Abundance #13811:1-Hexene, 4,5-dimethyl- $$ 4,5-Dimethyl-1-hexene 43 71

A A ।A 5000 55 4.60 4.80 5.00 5.20 5.40 27 m/z 41.05 65.40%

m/z-> 0—TPT 20 30 4 40 ' I 'I 50 —14 60 70 80 84 97 ■i■'■'i'■i ■ ■ ■ 1 i ■ ■ ■ ■i' ' ■ ■ i ’

90 100 110 120 130 Abundance #24321: Butanoic acid, 2-propenyl ester 43 71 AN 4.60 4.80 5.00 5.20 5.40 rn/ Z 69.10 58.48% A

5000 27

57 0 ■ i ■ ■ ■ ■ i ' 1 ■ ' 1'... 1,..... I1' | i 1 89 100..................... 128 m/z--> 20 30 40 50 60 701 80 90 100 110 120 130 Abundance #4280: Butane, 2,2-dimethyl- (CAS) $$ 2,2-Dimethylbutane $... -A_ 43 57 4.60 4.80 5.00 5.20 5.40 71 m/z 59.10 39.52%

5000

m/z--> 9 1 i 1 ' ' ' I 1 20 30 —++ +51 60 40 50 I I................. I 70 80 90 100 110 120 130 A ji 4.60 4.80 .AA 5.00 5.20 5.40 | /

320.D SCAN508.M Wed Jan 09 15:18:12 2002 Page 6

NYC-WTC_000051146