GCMS analysis results for sample AE00106, Feb 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN25\00106.D Vial: 5 Acq On : 25 Jan 2002 1:28 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 25, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 3 METHYLFULVENE Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

4.37 0.08 ug/L 36636 1,4-Dichlorobenzene-d4 9.71

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 METHYLFULVENE 92 C7H8 000000-00-0 9 2 1,3,5-Cycloheptatriene (CAS) $$ ... 92 C7H8 000544-25-2 9 3 Spiro[2,4]hepta-4,6-diene $$ Spi... 92 C7H8 000765-46-8 7 4 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 7 Abundance Scan 87 (4.367 min): 00106.D (-) m/z 91.00 100.00% 91

5000 85 4 00 4.20 4 40 460 4.80 39 43 51 65 ■ ■ । ■ • ■ ■ i ■ 11 *11 ■ । >111 > । ■ ।1 > > > । > * ■ ■ । > i • > m/z 92.10 67.89% mlz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5531: METHYLFULVENE 91

5000 4.00 4.20 4.40 4.60 4.80 m/z 85.00 19.91% -------- 1' 11" 111139 r - 65 m/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5568:1,3,5-Cycloheptatriene (CAS) $$ Cycloheptatriene $$... 91 ■ > । A A ‘ 'i' ■ ■ ■ ।■■ —RP 4.00 4.20 4.40 4.60 4.80 5000 m/z 43.10 12.97%

Tl/Z-> Abundance 30 35 39 , 65 11" " i " " i " " i"111"1 111111111111111186 40 45 50 55 60 65 70 75 80 85 90 111'11

#5553: Spiro[2,4Jhepta-4,6-diene $$ Spiro[2.4]hepta-4,6-diene 91 1 ■ i' ■ ■ ■ i ■ ■

95 100 A

m/z 4.00 / An Mo/) 4.20 4.40 39.00 4.60 4.80 11.91%

5000

m/z--> ■ । 30 39 51 65 61 . | 77 ■ i ■ • ■ • i • ■ ’ ■ i • ■ • • l ‘ ■ i • ■ ■ ■ i ■ ■ l. 11,.. ।.... ।■ 111111'' ■ 111 35 40 45 50 55 60 65 70 75 80 85 90 । ■ i ■ ■ ■ ■ i ■ ■ 95 100 Ml A......... , 4.00 4.20 4.40 4.60 4.80

00106.D SCAN508.M Mon Jan 28 09:49:53 2002 Page 5

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