GCMS analysis results for sample AE00106, Feb 2002

NYC 9/11 Public Portal Document

Data File : C: \MSDCHEM\1\5973N\02JAN25\00106.D Vial: 5 . Acq On : 25 Jan 2002 1:28 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 25, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N.L Peak Number 10 2-METHYTHIO-3-METHYL PYRAZINE Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

13.37 0.05 ug/L 31979 Naphthalene-d8 13.19 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-METHYTHIO-3-METHYL PYRAZINE 140 C6H8N2S 002882-20-4 78 O 2 Benzenethiol, 4-methoxy- $$ para... 140 C7H80S 000696-63-9 64 3 meta-Methoxybenzenethiol $$ 3-Me... 140 C7H8OS 015570-12-4 64 4 l-Oxetan-2-one, 4,4-diethyl-3-me... 140 C8H12O2 000000-00-0 56 WKO Abundance Scan 876 (13.375 min): 00106.D (-) m/z 140.10 100.00% 1-0

5000 T 1-r 70 94 13.00 13.20 13.40 13.60 13.80 84 7. 108 m/z--> ■ ' ■ i

40 ■ ■ ■ ■ i

50 ' 54— 60 .70I . 80 90 100 110 120 130 140 m/Z 70.00 16.06% Abundance #35180: 2-METHYTHIO-3-METHYL PYRAZINE 1.0

5000 107 ■ i ' ■ ■ ■ i ■ ■ ■ ■ i ■

13.00 13.20 13.40 13.60 13.80 125 42 m/z94.10 14.16% 66 - 84 98 ■ ■ ■ । ■ 1 । ■ ■ > ■ । ' 1 I ■ l > > ■ i ■ ■ • ■ i ■ • ■ ■ i ■ ■ - n/z-> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35296: Benzenethiol, 4-methoxy- $$ para-Methoxybenzenethi. .. 140 125 -+ AT 13.00 13.20 13.40 13.60 13.80 TIT

5000 m/z 96.10 9.71% 97 69 ' i 1 1 ii। 1 i 1 1 ' no 1 I ' 1 1 1 1 1 1 1 +1 m/z—> 40 50 60 70 90 80 100 110 120 130 140 Abundance #35298: meta-Methoxybenzenethiol $$ 3-Methoxythiophenol $$... *T Tit 140 13.00 13.20 13.40 13.60 13.80 m/z 66.00 9.18%

5000 97 125

66 110 ■ i ■ ' ' ■ i ' H 84 | ' I 1 1 1 ' I 1 ' 'I " 1 1T' 1 1 1 i 1 11 ' i1'''T1 Ti 40 50 60 70 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

00106.D SCAN508.M Mon Jan 28 09:49:54 2002 Page 12

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