GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB05\00028A.D Vial: 4 ‘ Acq On 5 Feb 2002 5:27 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 8 Benzenethiol, 4-methoxy- $$... Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 13.37 0.04 ug/L 45992 Naphthalene-d8 13.20 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzenethiol, 4-methoxy- $$ para... 140 C7H80S 000696-63-9 64 2 2-METHYTHIO-3-METHYL PYRAZINE 140 C6H8N2S 002882-20-4 64 3 2-methylmercaptophenol 140 C7H80S 000000-00-0 56 4 Pyrimidinetetramine- $$ Pyrimidi... 140 C4H8N6 001004-74-6 50 Abundance Scan 876 (13.375 min): 00028A.D (-) m/z 140.10 100.00% 140

5000 - 70 94 42 86 । 108 13.00 13.20 13.40 13.60 13.80

miz-> ol - 40 50 54.10 60 70 0 80 90 — 100 110 120 130 140 m/ Z 70.00 13.53% Abundance #35296: Benzenethiol, 4-methoxy- $$ para-Methoxybenzenethi... 140 125

5000 TT ■ i ■ ' 1 • i 1 97 13.00 13.20 13.40 13.60 13.80 m/z 94.00 12.15% 69 ii ....iio —— o! ■ ■ । ■ ■ ■ ■ । ■ ■' ■ ।■ hI''1' ।'■■■।■'I'। p....।.i 1130 ' m/z-> 40 50 60 70 80 90 100 110 120 140 Abundance #35180: 2-METHYTHIO-3-METHYL PYRAZINE 140 ■ i 1 ' 1 ' i ' 1 ■ 0 1 1 1 1 i 11 r i 1 13.00 13.20 13,40 13.60 13.80 5000 107 m/z 96.10 8.01% 125 42 84 66 98 Of ■ ' i I - I,....... II , , T-r1 m/z-> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35295:2-methylmercaptophenol - 1-0 13.00 13.20 13.40 13.60 13.80 m/ z 66.10 7.94%

5000 97 125

45 77 I 106 0 . TTTT - ' ■ i 1 ■ ' ■ i 1 ■ 1 ■ i 1 ■ ' ■ i ■ ' 1-—— ■ । ■ I ’ I1 • । . i . । . < < . । m/z-> 40 50 60 70 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

00028A.D HP020702.M Thu Feb 21 15:48:54 2002 Page 10

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