DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02FEB27\02386.D Vial: 2 Acq On : 27 Feb 2002 4:07 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l..-\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L

Peak Number 9 Benzenethiol, 4-methoxy- $$... Concentration Rank 11

R.T. EstConc Area Relative to ISTD R.T.

13.38 0.06 ug/L 48593 Naphthalene-d8 13.20

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzenethiol, 4-methoxy- $$ para... 140 C7H80S 000696-63-9 72 2 2-Methoxy-3-hydrazinyl-pyrazine 140 C5H8N40 000000-00-0 72 3 Phenol, 2-(methylthio) - 140 C7H8OS 001073-29-6 72 4 Pyrazine, 2-methyl-3-(methylthio... 140 C6H8N2S 002882-20-4 64 Abundance Scan 886 (13.376 min): 02386.D (-) m/z 140.00 100.00% 1-0

5000 .................. / ■ । । । ■ i ■ 54 70 94 108 ■ । ■ 1 ■ i ■ ■ ■ ■ 13.00 13.20 13.40 13.60 13.80 ob ............ pH.... 1I[ m/z 70.00 14.21% miz-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35296: Benzenethiol, 4-methoxy- $$ para-Methoxybenzenethi... 140 125

5000 97 13.00 13.20 13.40 13.60 13.80 m/ z 93.90 11.77% 69 Oh Il il , 110 ■ ' i ' 1 1 ■ i ' ' ' ■ । 1 1 1 ' I ■ ■ ' ■ i ■ ■ 1 ■ i ■ 1’11 । , ... i'. ... । . I ।........ Ti- II m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35089: 2-Methoxy-3-hydraziny!-pyrazine 14.0 - 13.00 13.20 13.40 13.60 13.80 5000 42 m/z 141.00 10.35% 54 68 80 95 108 121

m/z-> 0| ■ । । । | I 30 40 ■ 1 i ' 50 I,... I.... 1 ' i ' ' 60 70 80 90 — | | 100 110 120 130 140 "ti

Abundance #35277: Phenol, 2-(methylthio)- ■ i 1 ‘ ' i ‘ ■ > ■ i ■ > ■ ■ i ■ 1'0 13.00 13.20 13.40 13.60 13.80 m/z 54.10 8.90%

5000 125 97 45 0- 1 76 ■ • I ' 1 1 ■ 1 | 1 I ! ! [ ' l- | > ! 1 I | l ( 1 - TtI 107 I, - m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

02386.D HP022102.M Thu Feb 28 08:47:10 2002 Page 11

NYC-WTC_000005040