GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB05\30648A.D Vial: 5 Acq On 5 Feb 2002 2:03 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 9 Phenol, 2-(methylthio)- Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 13.37 0.05 ug/L 57676 Naphthalene -d8 13.20 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenol, 2-(methylthio) - 140 C7H80S 001073-29-6 64 2 2-methylmercaptophenol 140 C7H80S 000000-00-0 59 3 Benzenethiol, 4-methoxy- $$ para... 140 C7H80S 000696-63-9 59 4 Phenol, 4-(methylthio) - (CAS) $$... 140 C7H80S 001073-72-9 59 Abundance Scan 876 (13.375 min): 30648A.D (-) m/z 140.10 100.00% 140

5000

52 , 70 76 82 94 108 134 13.00 13.20 13.40 13.60 13.80 0- ............ .'|'I + "01 . H ! | . . . /1 I I . - .... H m/ z 70.00 10.03% miz-> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35277: Phenol, 2-(methylthio)- 140

— 5000- ■ ■ i 1 ' ' ' i ■ 97 125 13.00 13.20 13.40 13.60 13.80 45 rn/z 94.10 9.13%

miz-> 0- —L1 PHD ......... 40 107 !50 60 70 76

80 90 100 110 120 130 140 Abundance #35295:2-methylmercaptophenol 140

13.00 13.20 13.40 13.60 13.80 5000 m/z 141.10 8.12% 97 125

45 77 | 106 0 1 ■ । 1'1.......... ... 1 * ।j 11 * ।1 * ■ * । 1 ■ --- TPITITTTT -Rr-p-r — m/z-> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35296: Benzenethiol, 4-methoxy- $$ para-Methoxybenzenethi... ■ i ' ' 1 ■ i ' 1 ' ' l ' ' ' ‘ i ' 140 13.00 13.20 13.40 13.60 13.80 125 m/z96.20 7.58%

5000 97 1 69 0 ■ ■ i ' ■ ' 1 i ‘ ■ i ' ■ ' h1111 > ।11 ii 11111no 14 pi 111111 + I —— m/z-> 40 50 60 70 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

30648A.D SCAN508.M Thu Feb 21 10:19:05 2002 Page 11

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