DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02FEB27\02386.D Vial: 2 Acq On : 27 Feb 2002 4:07 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102. M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 10 2H-1,4-Benzoxazin-3(4H)-one.. Concentration Rank 13

R.T. EstConc Area Relative to ISTD R.T. 20.00 0.05 ug/L 39092 Acenaphthene-dl0 18.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2H-1,4-Benzoxazin-3(4H)-one (CAS... 149 C8H7NO2 005466-88-6 45 2 2H-1,4-Benzoxazin-3(4H)-one $$ 2... 149 C8H7NO2 005466-88-6 45 3 2-Propanone, 1-phenyl-, oxime (C... 149 C9H11NO 013213-36-0 45 4 5-(3-Methylbutyl)-2-pyridinecarb... 193 C11H15NO2 049751-50-0 39 Abundance Scan 1473 (20.002 min): 02386.D (-) m/z 149.00 100.00% 149

5000

177 43

m/z-> Abundance 01 a40 65 84 93 105 ■ ■ i '' 1 ‘ i 1 1 ' ■ i ' ■'' i11 ' ‘ i ■1111 11 ■ ■ i '' ■ ‘ i'1 ■ ■ i ‘ ■1 11 ‘ ■ 50 60 70 80 90 100 110 120 130 140 150 160 170 180 #45071: 2H-1,4-Benzoxazin-3(4H)-one (CAS) $$ 3,4-DIHYDRO-3... i ■ ' ■ ■ i 1 ' ' ' i ' ' 19.60 19.80 20.00 20.20 20.40 m/Z 176.90 20.12%

120 149

5000 19.60 19.80 20.00 20.20 20.40 65 79 m/z 43.10 14.71% 92 108 0- 1" 1111" 1111 PmT T’II m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #45072: 2H-1,4-Benzoxazin-3(4H)-one $$ 2H-1,4-Benzoxazin-3-on 120 149 1 ■ i 1 1 ’ I" ' ' I ' ' 19.60 19.80 20.00 20.20 20.40 5000 m/z 93.00 13.69%

65 79 92 108

niz- > o1 ........ . ...... ''ll'' I ■ ' ' 40 50 60 70 80 ' 111' 90 A "I""!'"1 ‘' i' ■'' i ‘'r r i'1 100 110 120 130 140 150 160 170 180 Abundance #45213:2-Propanone, 1-phenyl-, oxime (CAS) $$ 1-PhenyI-2-... _________ । । । ■ ■ ■ ■ f । । ' ■ i ' ■ 91 149 19.60 19.80 20.00 20.20 20.40 116 m/ Z 65.00 10.74%

5000 131

65 105 I ■ ■ 1 ‘ i ‘1 ■ ■ i 1'1 11 1 ' 0- 1111 ■1 ■ । ■1 ■ ■ ।1 ■' ■ ।1 ■ ■11 ■ ■ 1 ■ r 11 ■ i ■ ■ +TTT 1 111 ■ n/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 19.60 19.80 20.00 20.20 20.40

32386.D HP022102.M Thu Feb 28 08:47:10 2002 Page 12

NYC-WTC_000005041