GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB05\30644A.D Vial: 1 Acq On 5 Feb 2002 2:56 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 9 Benzene, (methylsulfinyl)- Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 13.37 0.05 ug/L 54249 Naphthalene-d8 13.20 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Benzene, (methylsulfinyl)- 140 C7H80S 001193-82-4 64 2 2 METHYL THIO 5 METHYL PYRAZINE 140 C6H8N2S 000000-00-0 64 3 Benzenethiol, 4-methoxy- $$ para... 140 C7H80S 000696-63-9 59 4 Benzene, (methylsulfinyl)- (CAS)... 140 C7H8OS 001193-82-4 50 Abundance Scan 876 (13.375 min): 30644A.D (-) m/z 140.10 100.00% 140

5000 .

40 52 70 84 1 108 13.00 13.20 13.40 13.60 13.80 ob . . i |'l ■ ■ . ! . . I . |......... li , , , I I , । , I । I rvi .. ......... HP m/z 94.10 13.54% m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35271: Benzene, (methylsulfinyl)- 125 140

77 5000 51 * 97 13.00 13.20 13.40 13.60 13.80 m/ z 70.10 10.43% 109 . oh ■ 1 i ■ 1 ' 1 ■ ' 1 I 1 ■ ' 1 1 1 ' 1 1 I ' 11 1 1 1 1 1 1 I ' 1 1 1 1 1 1 ‘ 1 1 ' 1 1 ' 1 1 1 ' -- vfz~> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35181: 2 METHYL THIO 5 METHYL PYRAZINE 140 4 13.00 13.20 13.40 13.60 13.80 5000 m/z 141.00 8.29% 66 72 94 57 । 84 ----- 107 oh ................... ■ ■ i ■ । | | । ■ • ■ ■ । ■ TII — - miz-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35296: Benzenethiol, 4-methoxy- $$ para-Methoxybenzenethi... 140 13.00 13.20 13.40 13.60 13.80 125 m/z 96.10 7.88%

5000 97 69

m/z-> Oh 30 40 50 60 70 80 ............ ...I!.... 90 100 110 120 130 I— 140 13.00 13.20 13.40 13.60 13.80

30644A.D SCAN508 .M Fri Feb 22 11:44:25 2002 Page 11

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