GCMS analysis results for sample AD31676, Jan 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN23\31676.D Vial: 1 Acq On : 23 Jan 2002 2:57 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 22, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1... \ SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 1,4-Benzenediamine, N,N,N'-. Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T.

20.93 0.10 ug/L 59019 Phenanthrene-dl0 22.65

Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 1,4-Benzenediamine, N,N,N'-triet... 192 C12H20N2 024340-91-8 47 2 cis-anti-cis-10,10-Dimethyltricy. .. 192 C13H20O 000000-00-0 23 3 Allyloxydicyclopentadiene 188 C13H160 000000-00-0 10 4 3-Fluoro~5-(trifluoromethyl)benz... 192 C8H4F4O 000000-00-0 10 Abundance Scan 1538 (20.933 min): 31676.D (-) m/z 177.10 100.00% 177 192 41 163 248 5000 55 66 83 128 205 233 96 20.60 20.80 21.00 21.20

nz-> 01 1 ‘ i 40 — 60 P 80 i ■ ■ ' ■ i ■ 100 120 140 160 180 200 220 240 ■ ' i ■ ■ ■ ■ i ■ ■ ■ ■ i 1 1 ■ i 1 ■ ■ ■ i 1 1 • ■ i ■ m/z 191.80 73.92% Abundance

5000 #103340: 1,4-Benzenediamine, N,N,N’-triethyl-$$ p-Phenyle...

66 106 ... 177

133 148 192 k 20.60 20.80 21.00 21.20 ' ‘ 119 163 m/z 191.10 69.37% 80 0+ »* । • * * < । * * * I * * * > । i » » * । < * * * i • ■ 1 i ■ ■ • ■ i ■ ■ 1 i ■ ■ ■ ■ i ■ • ■ • I ■ ■ m/z-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #103596: cis-anti-cis-10,10-Dimethyltricyclo[6.3.0.0(2,6)]... 41

20.60 20.80 21.00 21.20 5000 67 m/z 41.10 65.40% 192 53 109 136 149 163

Of ■ ■ ।1 ■ ■ i • ■ ■ ■ i • 1 71. 1 1 ' i 1 1 1 ' I ' 1 1 || i ■ ■ • ■ i ■ ■ ■ 1 i ■ ■ ■ i ■ ■ ■ ■ i ■ 1 ■ ■ i ■ ■ niz-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #98483: Allyloxydicyclopentadiene 43 66 20.60 20.80 21.00 21.20 m/z 43.10 60.27% 5000 79 78 90 104 A 131 147 121

iz—> o- 40 60 1|. L 80 100 120 140 188 ■ । ■ ■ ■ • i • ■ 1 ' i 1 1 ■ ■ i ■ ■ ■ 1 i ‘

160 180 200 220 • i • ■

240 20.60 20.80 21.00 21.20

31676.D SCAN508.M Thu Jan 24 09:57:33 2002 Page 7

NYC-WTC_000050327