GCMS reference analysis AE08209, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\APR1702\REFA1.D Vial: 17 Acq On : 17 Apr 2002 11:51 pm Operator: Sample : gc/ms scan 4/8 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 18 13:54 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 436730 20.00 ug/1 -0.03 10) Naphthalene-d8 15.85 136 1560282 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.14 164 884115 20.00 ug/1 -0.03 30) Phenanthrene-diO 25.59 188 1230116 20.00 ug/1 -0.03 39) Chrysene-dl2 33.64 240 737355 20.00 ug/1 -0.04 45) Perylene-dl2 37.87 264 493984 20.00 ug/1 -0.05

System Monitoring Compounds 2 8) TCMX 23.28 209 34220 7.72 ug/L -0.05 Spiked Amount 10.000 Recovery = 77.20% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.86 74 76226 8.02 ug/1 99 3) bis(2-Chloroethyl)ether 11.61 93 190206 12.86 ug/1 97 4) 1,3-Dichlorobenzene 12.11 146 199653 13.09 ug/1 98 5) 1,4-Dichlorobenzene 12.26 146 203013 13.22 ug/1 98 6) 1,2-Dichlorobenzene 12.77 146 194588 13.65 ug/1 99 7) 2,21 -oxybis(1-Chloropropan 13.09 45 258569 12.65 ug/1 98 8) N-Nitroso-di-n-propylamine 13.48 70 120961 12.47 ug/1 96 9) Hexachloroethane 13.62 117 67621 12.02 ug/1 98 11) Nitrobenzene 13.89 77 160757 11.75 ug/1 95 12) 1sophorone 14.53 82 288972 11.16 ug/1 100 13) bis(2-Chloroethoxy)methane 15.22 93 233553 13.85 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 173406 14.62 ug/1 99 15) Naphthalene 15.90 128 538231 14.35 ug/1 99 16) Hexachlorobutadiene 16.44 225 85819 14.47 ug/1 98 18) Hexachlorocyclopentadiene 18.64 237 11897 3.04 ug/1 90 19) 2-Chloronaphthalene 19.40 162 338096 14.50 ug/1 98 20) Dimethylphthalate 20.49 163 455549 16.95 ug/1 99 21) 2,6-Dinitrotoluene 20.70 165 81554 12.69 ug/1 99 22) Acenaphthylene 20.68 152 468062 14.35 ug/1 100 23) Acenaphthene 21.24 153 353239 15.23 ug/1 99 24) 2,4-Dinitrotoluene 21.88 165 94885 11.21 ug/1 99 25) Diethylphthalate 22.62 149 432488 16.77 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 199706 17.46 ug/1 98 27) Fluorene 22.76 166 394293 16.06 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 344873 12.64 ug/L 94 31) N-Nitrosodiphenylamine 23.17 168 123194 12.04 ug/1 97 32) 4-Bromophenyl-phenylether 24.25 248 109371 18.31 ug/1 95

(#) = qualifier out of range (m) = manual integration REFA1.D GCMS0412.M Thu Apr 18 13:57:27 2002 Page 1

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