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GCMS results for sample AE08069, Apr 2002

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of sample AE08069 including surrogate recovery and unknown compounds on April 18, 2002.

NYC-WTC_000046841–000046854

Folder label: “GCMS X 4/5/02 A 4/16/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C : \MSDCHEM\1\DATA\020415\08069.D Vial: 26 Acq On : 16 Apr 2002 7:13 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 5 Bitoscanate Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.24 ug/L 250685 Phenanthranene-dl0 23.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Bitoscanate 192 C8H4N2S2 004044-65-9 53 2 Pyrazine, tetraethyl- 192 C12H20N2 038325-19-8 53 3 1,2-Phenylene diisothiocyanate 192 C8H4N2S2 071105-17-4 50 4 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 50 Abundance Scan 3330 (22 645 min) 08069.D (-3318) (-) m/z 192.30 100.00% 192

5000

1 TIT 40 _ RR 82 96 146 160 22 40 22 60 22 80 23 00

n/z- > 0 0J . ............. l| r 20 । 1, . Ji . Il.......... .... । /I, ... ........... 40 60 80 100 120 140 160 180 1 200 m/z 191.30 22.66% Abundance #125828 Bitoscanate 19 2

- 5000 I ' ' 1 1 I 22.40 22.60 22 80 23 00 134 m/z 146.30 16.33% 160 A n 50 6 3 7 5 90 1 02 122 148 176 0— ----- -Hi ■ ■ ।180i ■ 1 160 Tl/Z—> 0 20 40 60 80 100 120 140 200 Abundance #80990: Pyrazine, tetraethyl- 192 177

22 40 22 60 22 80 23 00 5000 m/z 193.30 13.94% 41 67 53 29 81 149 163 0- 11 ‘‘‘ I 93 107 121 133 --**I 11" ' ' 'l“ l ' —— Tl/Z—> 0 20 40 60 80 100 120 140 160 180 200 Abundance #80862: 1,2-Phenylene di isothiocyanate 192 22.40 22.60 22 80 23.00 m/ z 40.20 12.96% 64 5000

50 90 134 39 75 0 4 0 ' ' 1828 Ip —+ llL Jl—P । 107116 | 148 160 — 4—200 Tl/Z--> 20 40 60 80 100 120 140 160 180 22.40 22.60 22 80 23.00

08069.D 041202SCAN.M Tue Apr 16 13:58:31 2002 Page 8

NYC-WTC_000046852

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NYC-WTC_000046852Source: NYC Law Department, mirrored locally

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