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GCMS analysis results for sample AE10308, May 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10308 conducted on May 17, 2002.

NYC-WTC_000045171–000045188

Folder label: “GCMS X 5/1/02 A 5/8/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\10308.D Vial: 11 Acq On 8 May 2002 9:56 pm Operator: Mclean Sample 5/1 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 5 Bitoscanate Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 22.58 0.26 ug/L 298986 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Bitoscanate 192 C8H4N2S2 004044-65-9 53 2 2,5-Dihydrophosphole, 3-methyl-l... 192 C11H13OP 1000196-97-5/45 3 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 45 4 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 42 Abundance Scan 3319 (22.580 min): 10308.D (-3308) (-) m/z 192.10 100.00% 192

5000

92 96 146 .... 1... . OZ I | 160 22.20 22.40 22.60 22.80 23.00 42 70 | । I । । | ! I । । | ’ I ! I | I I ! I | I I ! ! | I I ! I | I i'l I | 0 v TIPTTH I I I I [ I I i i I I I I I I I I 1 I I m/z 191.00 21.29% Ti/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125828: Bitoscanate 192

5000 1 । 1 1 ' 1 । ' ' I 1 ' 1 1 i ■ 1 1 i ' 22.20 22.40 22.60 22.80 23.00 134 m/ Z 96.00 14.29% 90 160 .n 50 63 75 102 122 .. 148 .., 01 "I" -HHH +++ 176 ।"11111" ।THT mfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80965: 2,5-Dihydrophosphole, 3-methyl-1-oxo-1-phenyl- 192 164 ■ । 1 1 ■ ‘ । ■ 1 1 1 i ■ ■ IT 22.20 22.40 22.60 22.80 23.00 5000 99 m/z 193.10 13.48% 115 47 77 177 67 125 134 146 27 38 57 , 0 I | I I I | | r i TI rl • J 1 I I I' I I I I I + I r mrrl rl +44—44 Tirti I 1 55 ++4159— / mz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80950:1,5-Naphthalenedithiole 1 i 11 1 r i 1 1 1 1 i ‘ ' 1 1 i 1 1 1 1 i ' 192 22.20 22.40 22.60 22.80 23.00 m/ z 146.10 13.06% A 5000 115 128 159 40 57 69 79 147

m/z-> o 6,1061— Ji 11'1111 111 177 TOguur Trp-r ,10........ a 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10308.D 050102.M Thu May 09 13:52:31 2002 Page 8

NYC-WTC_000045183

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NYC-WTC_000045183Source: NYC Law Department, mirrored locally

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