GCMS analysis results for sample AE08067, Apr 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\020415\08067.D Vial : 24 Acq On 16 Apr 2002 5:36 am Operator: Nefliu Sample sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 Acetic acid, 3 -[1,3]dioxola.. . Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 5.96 0.40 ug/L 223715 1,4-Dichlorobenzene-d4 9.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3- [1,3]dioxolan-2-y. . . 174 C8H1404 1000186-02-3 33 2 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 9 3 1,3-Dioxolane 74 C3H602 000646-06-0 7 4 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 7 Abundance Scan 490 (5 958 min) 08067 D (-482) (-) m/z 73.30 100.00% 73

5000 ... ....... ........ 43 5 60 5 80 6 00 6 20 6.40 ___i 1Mil, 55 ii 11 ______87 . 01 ' i " 11 r r 1 ■ i' ' ' 11 I ' ' " I 1 1 ' ' I " ' । | 1 । । 1 J । I ' । | I "T"’V’ I | I I I I | । I I I | I I I I | I I I I | I >>■ | r | . . m/z 43.30 27.62% n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #25344. Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73

5000 5 60 A y. 5 80 6 00 6 20 6.40 43 m/z 40.20 14.49% 27 I 87 113 ■ i ■ ■ ■ 131 174 01 ' i ■ ■ '' r ■■ly,,, ‘hr 55 ,7,-, ।. ‘I’I I > ■ i ■ ■ i". । ■ ■ ■ ■ i • • ■ ■ i ■ i ■ • ■ ■ । -1 > > i' T Tl/Z--> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #114875. 3-Pentanol, 3-methyH 73 5.60 5.80 6.00 6.20 6.40 5000- m/ z 41.30 12.11% 27 45 55 87 15 1137, 1 . .. 63 63 ,, 0) i i । । i'i t | it I I | I I । r| I I i r rtmr । i i i |‘t n/z- > 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance __ #25276: 1 3-Dioxolane 1 ■ । 1 ' 73 5 60 5 80 m/ z 45.20 9.17% 29 44 5000

in

n/z-> 0 ■ i11 ■1 r 10 20 +430—40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 56 " l' " ' l111111 '■" I " 11 1111 'T ■ ■ । ■' > ■ । ■ ■ ■ ■ । ■ • ■ ■ । ■11 ■ ■1 ■ i ■ ■ ■ ■ । ■ 5.60 5 80 6.00 6.20 6.40

08067.D 041202SCAN.M Tue Apr 16 13:56:07 2002 Page 6

NYC-WTC_000046808