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GCMS analysis results for sample AE07976, April 18, 2002

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Laboratory report documenting GCMS analysis of sample AE07976 conducted on April 18, 2002.

NYC-WTC_000047593–000047607

Folder label: “GCMS X 4/4/02 A 4/15/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\020415\07976.D Vial : 16 Acq On 15 Apr 2002 11:05 pm Operator: Nefliu Sample sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 Acetic acid, 3-[1,3]dioxola... Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 5.97 0.50 ug/L 389109 1,4-Dichlorobenzene-d4 9.99 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 1000186-02-3 33 2 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 33 3 Pentanol, 5-amino- 103 C5H13NO 002508-29-4 9 4 N-Ethylformamide 73 C3H7NO 000627-45-2 9 Abundance Scan 492 (5.970 min): 07976 D (-485) (-) m/z 73.30 100.00% 73

5000 43 5 60 5 80 6 00 6 20 6.40 ol ...................... ... I 87 103 TTTTTITNITTDTTTTTIDWTTLTWTUTTPTTLTTTTTTT m/z 43.30 26.89% n/z— > 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #25344: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73

5000' ' I n 1-1 1 5 60 5 80 A 6.00 T’atIm 6.20 6.40 43 m/ z 45.30 11.07% 55 27, 87 113 131 174 0 - ■ । ■1" ।" ■ ‘,I’i BITETTIPTTTTDTITTTTT n/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #114875 3-Pentanol, 3-methyl- 73 ........................ ..... ..............................

5 60 5 80 6 00 6.20 6.40 5000 m/z 41.30 10.34% 55 27 45 87

n/z— > 15 1371 ol Tmm , 63 10 , , .7"1! |‘I., |, 20 30 40 50 60 +4 I ■' ’ ’ I v V 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #108252 Pentanol, 5-amino- , l MA,. ——4-44 30 5 60 5.80 6 00 6 20 640 m/z 71.30 7.18%

5000

...... ti 11‘8 ... 103........................... 41,, 56 67 0 ■ i " " r 1 1111-1"‘1"‘011101-03""TT"TET‘STTTCOIOOTTTITITTT n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5 80 6 00 6 20 6 40

07976.D 041202SCAN.M Tue Apr 16 13:46:09 2002 Page 7

NYC-WTC_000047603

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NYC-WTC_000047603Source: NYC Law Department, mirrored locally

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