GCMS reference analysis results for sample AE07311, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\APR0302\1965.D Vial: 6 Acq On 3 Apr 2002 5:35 pm Operator: Sample re-extract Inst : GC/MS 209 Misc Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0403.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 3-Hexanone Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T. 6.84 1.08 ug/1 119200 1,4-Dichlorobenzene-d4 12.25 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Hexanone 100 C6H120 000589-38-8 64 2 3 -Pentanone, 2-methyl- 100 C6H120 000565-69-5 40 3 2,4-Pentanedione 100 C5H802 000123-54-6 38 4 Tridecane_________ 184 C13H28 000629-50-5 28 Abundance Scan 196 (6.842 min): 1965.D (-) m/z 43.05 100.00% 43 57 11

1 71 5000- 100 ) ‘ ‘T -m । . . , , । ' t=T 6.40 6.60 6.80 7.00 7.20

mlz-> r " ■ i ■' ‘' i 34+1 — TTTr 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 49 1 ■ i1 ■■ ■ ।"111 H 85 — 111'' I r m/ z 57.00 91.25% Abundance #63357:3-Hexanone 43 57 29

5000 71 6.40 6.60 6.80 7.00 7.20 100 m/z 71.00 62.44%

111'' [ T 1 r 1111" " i' I I I I I I 1 I I I I I I I MM| 85, 0 Tp-rrrp m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #63398: 3-Pentanone, 2-methyl- 57 43 6.40 6.60 6.80 7.00 7.20 5000 m/z 100.05 39.39% 100 71

r...... +38 1 ................I1 85 1' i " " i " 1 r i " ' i1" 1 r "' I " " i " “ i " '1

JU Tyrrrrp m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #63324:2,4-Pentanedione I ■ ■ ’ ■ I ' ■ • I 1 1 1 ' I ■ > I 1 I 43 6.40 6.60 6.80 7.00 7.20 m/z 41.05 27.01%

5000

m/z—> ...... 27....... 38 || l~| i r i i । < i i i | i 58 I I I I I I I I I I I >1 I I I I I I I < I I I I iI r[ii i i ।i 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 72 i [ i I I I | r I l'T r T 85 100

i " " I " 11 11111 " i' 6.40 6.60 6.80 L 7.00 7.20

1965.D GCMS0403.M Tue Apr 09 13:07:23 2002 Page 1

NYC-WTC_000046598