GCMS reference standard results for volatile organics, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\020513\0507REF1.D Vial: 7 Acq On : 13 May 2002 6:27 pm Operator: Nefliu Sample : 05/07 ref Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: rteint.e Quant Time: May 14 15:50:20 2002 Quant Results File: SCAN020507.RE

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Last Update : Thu May 09 09:21:01 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.38 152 448589 40.00 ug/1 -0.01 10) Naphthalene-d8 16.54 136 1683026 40.00 ug/1 -0.03 17) Acenaphthene-diO 24.46 164 896607 40.00 ug/1 -0.02 30) Phenanthrene-dlO 31.72 188 1549660 40.00 ug/1 -0.02 38) Chrysene-dl2 39.94 240 1215627 40.00 ug/1 -0.04 44) Perylene-dl2 43.16 264 741489 40.00 ug/1 -0.02

System Monitoring Compounds 27) TCMX 27.54 207 67650 9.45 ug/1 -0.04 Spiked Amount 10.000 Recovery = 94.50%

Target Compounds Qvalue 2) N-nitrosodimethylamine 3.99 74 49335m 6.90 ug/1 3) bis(2-Chloroethyl)ether 10.65 93 305594 17.61 ug/1 94 4) 1.3-Dichlorbenzene 11.12 146 244098 16.85 ug/1 98 5) 1,4-Dichlorobenzene 11.44 146 256515 16.22 ug/1 98 6) 1,2-Dichlorobenzene 11.96 146 248468 18.10 ug/1 98 7) 2,2'oxybis(1-Chloropropane 12.78 45 529445m 19.10 ug/1 8) N-Nitroso-di-n-propylamine 13.25 43 238705 19.23 ug/1 96 9) Hexachloroethane 13.26 119 95220 13.88 ug/1 98 11) Nitrobenzene 13.67 77 376410 18.63 ug/1 99 12) Isophorone 14.78 82 761395 21.63 ug/1 99 13) bis(2-Chloroethoxy) methan 16.02 93 395840 18.93 ug/1 98 14) 1,2,4-Trichlorobenzene 16.39 180 213495 17.68 ug/1 93 15) Naphthalene 16.62 128 828044 19.63 ug/1 99 16) Hexachlorobutadiene 17.40 225 115650 16.50 ug/1 95 18) 2-Chloronaphthalene 21.93 162 456887 21.40 ug/1 99 19) Acenaphthylene 23.75 152 744376 17.87 ug/1 98 20) Dimethyl phthalate 23.84 163 559158 20.08 ug/1 98 21) 2,6-Dinitrotoluene 23.96 77 49093 20.47 ug/1 95 22) Acenaphthene 24.60 153 485884 20.12 ug/1 95 23) 2,4-Dinitrotoluene 25.73 165 120520 18.80 ug/1 99 24) Fluorene 27.01 166 579482 20.87 ug/1 99 25) Diethyl phthalate 27.22 149 620639 22.16 ug/1 99 26) 4-Chlorophenyl-phenylether 27.35 204 268299 19.50 ug/1 98 28) N-Nitrosodiphenylamine 27.94 168 167784 18.54 ug/1 100 29) Azobenzene 28.03 77 788314 18.42 ug/1 99 31) Hexachlorobenzene 29.60 284 166456 20.36 ug/1 98 32) 4-Bromophenyl-phenylether 29.71 248 159451 19.93 ug/1 91 33) Phenanthrene 31.82 178 798466 20.26 ug/1 98 34) Anthracene 32.05 178 715654 17.93 ug/1 100 35) Di-n-butylphthalate 34.81 149 1015944 20.60 ug/1 99

(#) = qualifier out of range (m) = manual integration 0507REF1.D SCAN020507.M Tue May 14 15:50:55 2002 Page 1

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