GCMS analysis results for sample AE10702, May 20 2002

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Data File : C:\MSDCHEM\l\DATA\020513\10702.D Vial: 13 Acq On : 14 May 2002 12:24 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C: \MSDCHEM\1\METHODS\SCAN020507 .M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 9 1,1,1,5,7,7,7-Heptamethyl-3... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

32.19 0.34 ug/1 41412 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l l,l,l,5,7,7/7-Heptamethyl-3,3-bi... 444 C13H40O5Si6 038147-00-1 23 2 Hexasiloxane, 1,1,3,3,5,5,7,7,9,... 430 C12H3805Si6 000995-82-4 12 3 Morphinan, 7,8-didehydro-4,5-epo... 429 C23H35NO3Si2 055449-66-6 10 4 Guaifenesin di-tms derivative 342 C16H3004Si2 1000137-06-7 9 Abundance 7)3 7 Scan 4955 (32.193 min): 10702.D (-4946) (-) m/z 73.05 100.00%

5000

147 221 —IpfATTTI 35 4188, 249 2013004355 430 1475 E 31.80 32.00 32.20 32.40 32.60 m/z 221.10 19.25% ' ■' I 1 1 111 ‘ I ■ 1 1 m/z-> 50 100 150 200 250 350 400 450 Abundance #26950: 1,1,1,5,7,7,7-Heptamethyl-3,3-bis(trimethylsiloxy)... 70

147 5000 267 1 i ■ ■ ■ 1 i 1 ■ 355 429 31.80 32.00 32.20 32.40 32.60 45 207 m/z 147.10 18.60%

n/z-> "T 50 I TDBBkk#.rd./..".1.".d..kT 100 150 200 250 L ..... — 300 350 400 450 Abundance #27715: Hexasiloxane, 1,1,3,3,5,5,7,7,9,9,11,11-dodecamethyl- 73 H ........... A r I ' > 1 • l ■ A AA ‘ I 1 1 ' 'I ' ' 31.80 32.00 32.20 32.40 32.60 5000 m/z 430.10 10.61% 207 281 133 341 A4E 103 .. | 177,[ 14 220 253 228, 7,4 309 [ L — —————— 415 rn/z-> Abundance 50

7)3 100 150 200 250 300 350 400 450 #27552: Morphinan, 7,8-didehydro-4,5-epoxy-17-methyl-3,6-b... ...... III.......... 31.80 32.00 32.20 32.40 32.60 m/z 428.90 9.89% 236 5000 146 196 429 1 287 . —507 94100115 150— 12.l1.2s.. , 1,3652372 I J 1 i ’ '"I 1 1 ’ 1 I " l-’-1 ’ • r | 1 । । । ■ n/z-> 200 250 300 350 400 450 31.80 32.00 32.20 32.40 32.60

10702.D SCAN020507 .M Wed May 15 08:44:12 2002 Page 11

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