GCMS sample analysis results for AE10606, May 10 2002

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Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050702\10606.D Vial: 11 Acq On 7 May 2002 9:17 pm Operator: Mclean Sample 5/3 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98 . L

Peak Number 5 Trisiloxane, 1,1,1,5,5,5-he... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

20.69 0.25 ug/L 302813 Acenapthalene-dlO 18.57

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H3604Si5 003555-47-3 38 2 Benzoic acid, 2,4-bis[(trimethyl... 370 C16H30O4Si3 010586-16-0 32 3 Noradrenaline tetraTMS 457 C20H43NO3Si4 068595-65-3 32 4 Phenethylamine, N-methyl-.beta., .. . 3 99 C18H37NO3Si3 010538-85-9/25 Abundance Scan 2997 (20.688 min): 10606.D (-2990) (-) m/ z 73.10 100.00% 73

5000 355 147 221 281 45 , [ 327 401 20.40 20.60 20.80 21.00

m/z-> +50— I 1‘ 100 ] 150 I 200 r I 250 II r 300 | 350 I 400 ‘ 1 1 II l f 1 1 1 I 13 I I FT 1 rT1 I 1 1 1 r 1 1 1 m/z 355.00 40.11% Abundance #26961: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trime... 73 147 281 — 5000 20.40 20.60 20.80 21.00 369 m/z 147.00 38.75% 45 207 20 310 341 | — 95 117 1 I"I‘ " Tt . . 177. . 249, i । i r । a * B y kl 1 ■ i > ■ ■ ■ i ■ " ■ ■ i ■ Tl/Z-> 50 100 150 200 250 300 350 400 Abundance #115312: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trim... 73

20.40 20.60 20.80 21.00 5000 355 m/z 221.10 37.80% 45

16 105 133,163 193 223 251 ,281 321 I—r rn/z-> 50 100 150 200 250 300 350 400 Abundance #27959: Noradrenaline tetraTMS ■ ■ 1 ■ ■ ... 73 20.40 20.60 20.80 21.00 m/z 281.10 21.03%

5000 102 355

45 147 442 1 I I I I I I I I I I I I I I I-I I < I L r I I I I 1 I I I I I 1 ' 1 _________________ 1-1 1 1 ' ' ' I ' j 1 1 I ' 1 ' ' 1 1 ' /z-> 50 100 150 200 250 300 350 400 20.40 20.60 20.80 21.00

10606.D 050102.M Thu May 09 09:12:01 2002 Page 8

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