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GCMS analysis results for sample AE10305, May 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10305 conducted on May 17, 2002.

NYC-WTC_000045113–000045136

Folder label: “GCMS X 5/1/02 A 5/8/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\l\DATA\050802\10305R.D Vial: 26 Acq On 9 May 2002 12:56 pm Operator: Mclean Sample re-inj Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 10 Trisiloxane, 1,1,1,5,5,5-he... Concentration Rank 15

R.T. EstConc Area Relative to ISTD R.T. 34.37 0.24 ug/L 184396 Perylene-dl2 34.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H3604Si5 003555-47-3 32 2 2-(2,6,6-Trimethylcyclohex-l-eny... 222 C14H22O2 1000185-64-1 22 3 Valeraldehyde, (o-nitrophenyl)hy... 221 C11H15N3O2 005977-70-8 9 4 .alpha.-Tetraloxime, 5,6-dimethoxy- 221 C12H15NO3 1000125-87-9 9 Abundance Scan 5325 (34.367 min): 10305R.D (-5316) (-) m/ z 73.10 100. 00% 73 221 147

5000 281

44 355 A AAAA MMMA4 A4. MiA/MaanNMAY 96 429 34.00 34.20 34.40 34.60 34.80 0- I T ' kL1 1—1 1 i 1 ‘ । i < r kit ' ■ 1 1 1 1 1 _L m/z 221.10 83.50% m/z-> 50 100 150 200 250 300 350 400 Abundance #26961: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trime... 73 147 281 5000 34.00 34.20 34.40 34.60 34.80 369 m/z 147.10 80.00% 45 0- ■ r ‘ 95 117 | i 177,227226 2l9 i 1 [ .1 13101 1 13411 1 1| 1 1 1 1 1 m/z-> 50 100 150 200 250 300 350 400 Abundance #66034: 2-(2,6,6-Trimethylcyclohex-1 -enyl)cyclopropanecarb... 147 A 34.00 34.20 34.40 34.60 34.80 107 5000 175 207 m/z 281.10 44.39% 41 79

0- LQllh ,, ill. । ,1,1, m/z-> 50 100 150 200 250 300 350 400 Abundance #126930: Valeraldehyde, (o-nitrophenyl)hydrazone 211 34.00 34.20 34.40 34.60 34.80 77 52 m/z 355.10 28.90% 5000 161 104 135

0 L I 11 k l 4 d i | , 186 ' 1 ' i 1 1 1 1 ' 1 1 1 1 1 ■ ' 1 1 1 ' ' 1 1 m/z-> 50 100 150 200 250 300 350 400 34.00 34.20 34.40 34.60 34.80

10305R.D 050102.M Thu May 09 13:51:07 2002 Page 13

NYC-WTC_000045130

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NYC-WTC_000045130Source: NYC Law Department, mirrored locally

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