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GCMS analysis results for unknown compounds, sample AE09093, May 2002

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Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE09093 on May 10, 2002.

NYC-WTC_000044902–000044925

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\9093 .D Vial: 15 Acq On 9 May 2002 2:49 am Operator: Mclean Sample 4/30 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 8 Trisiloxane, 1,1,1,5,5,5-he... Concentration Rank 13

R.T. EstConc Area Relative to ISTD R.T. 33.08 0.23 ug/L 176818 Perylene-dl2 34.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Trisiloxane, 1,1,1,5,5,5-hexamet... 384 C12H3604Si5 003555-47-3 2 Pyridine, 3,5-dichloro- 147 C5H3C12N 002457-47-9 7 3 Benzophenone-2,45-tricarboxyli... 356 C19H1607 1000098-5 5-8 5 4 Benzene, l-fluoro-3(2-cyanoethenyl) 147 C9H6FN 082344- 56-7 5 Abundance Scan 5105 (33.074 min): 9093. D (-5085) (-) m/z 73.10 100.00%

A 73 147 221

281 355 5000 429 49 96 “f).. , ffl/,. Al

A 1 ' 1 1 1

m/z-> Abundance o! i 1 50 L100 150 1 1 ' 200 250 300 350 #26961: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trime... TB1 400 32.80 33.00 33.20 33.40 m/z 147.10 94.84%

73 147 281 5000 ’’ I I II I 1 I I I II I I I I I I I III

32.80 33.00 33.20 33.40 369 m/z 221.10 83.46% 45 0- 95 117 - v-r 1 196 249 177 207226 r* , -"i 1 310 i ■ ' 341 ' ■ i 1kl [ 1 I ' m/z--> 50 100 150 200 250 300 350 400 Abundance #66200: Pyridine, 3,5-dichloro- 147 32.80 33.00 33.20 33.40 112 m/z 281.00 51.65%

A 5000 50

0 - 11 Ti 1 Tkl 1 I-1 m/z-> 50 100 150200 250 300 350 400 Abundance #87897: Benzophenone-2,4',5-tricarboxylic acid, trimethyl... 211 32.80 33.00 33.20 33.40

M 163 m/z 355.00 47.28% 5000 356 325 76 103 135 0 , I ,1, 171 I, 1 1 1 1 1 1 , 1 1 1 1 1 1 1 1 | ' 1 1 1 ■ 1 ’ I’’ I’ n/z—> 50 100 150 200 250 300 350 400 32.80 33.00 33.20 33.40

9093.D 050102.M Thu May 09 13:33:31 2002 Page 11

NYC-WTC_000044917

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NYC-WTC_000044917Source: NYC Law Department, mirrored locally

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