GCMS analysis results for sample AE10304, May 2002

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Data File C:\MSDCHEM\1\DATA\050802\10304 .D Vial: 7 Acq On 8 May 2002 6:41 pm Operator: Mclean Sample 5/1 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 11 2-Propenal, 3-(3,4-dimethox... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.26 ug/L 252246 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42 2 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 42/ 3 1,3-Benzodioxole, 4-methoxy-6 -(2. . . 192 C11H1203 000607-91-0 40 4 (+)-Calycotomine 223 C12H17NO3 1000127-35/0 36 Abundance Scan 3318 (22.574 min): 10304.D (-3312) (-) m/z 192.10 100.00% 192

5000

146 ................../। ............ ■ i ■ । 1 ■ i ■ ■ । ....... ■ ■ ■ < । ■ ■ > ■ । ■

66 118 02 96 160 22.20 22.40 22.60 22.80 23.00

m/z-> 0 144, ' " I r 11 L i i; I I i i । i I I r। i i Lt. 11 r ■1 M '11 ■ i 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ।11111 m/z 146.10 18.74% Abundance #80953: 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 161

5000 A.... ...... 22.20 22.40 22.60 22.80 23.00 77 91 121 149 177 m/z 191.10 18.25%

n/z-> 0 - 52 64 4 103

:30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 138 I' " 11 4 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192 i । । । I | । । । । 1 11 । i r । i i I r । i 22.20 22.40 22.60 22.80 23.00 5000 m/z96.00 14.86%

134 0i 45 11111111L1111111 682 90 108 122 -HH 1 PT ! | 148 160 । । । । r। । । . । । I | < > । । | . । 'I । । । । । । । । 11 । । I..... " 111 /z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80895:1 3-Benzodioxole, 4-methoxy-6-(2-propenyl)- T t | I I I I | I I Tv [ I I I I ] I IT 192 22.20 22.40 22.60 22.80 23.00 m/z 193.10 12.15% 5000

91 165 119 124 .

0 4 51 T 7 39 ------ . . .... . 103 I, ............... IL । 131 147 i | । । I I | I i I I j I I i r | I । < I । I i '1 11 11111 11 111 ' ‘' I11' 1 i I ’ ' 1 1 I 1 m/z-> : 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10304.D 050102.M Thu May 09 13:50:25 2002 Page 14

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