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GCMS analysis results for sample AE10304, May 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10304 conducted on May 17, 2002.

NYC-WTC_000045092–000045112

Folder label: “GCMS X 5/1/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\10304.D Vial: 7 Acq On 8 May 2002 6:41 pm Operator: Mclean Sample 5/1 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 12 Phenanthrene-diO Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T. 23.11 0.40 ug/L 384653 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual, 1 Phenanthrene-diO 188 C14D10 001517-22- 87 2 3-Amino-4-methyl-6-methoxyquinoline 188 C11H12N2O 1000213-71-' 3 2-Quinolinecarboxaldehyde, 8-hyd... 188 C10H8N2O2 005603-22-5 42 4 1-Naphthalenecarboxylic acid, 7-... 188 C11H803 002623-37-2 40 Abundance Scan 3409 (23.109 min): 10304.D (-3402) (-) m/z 188.15 100.00%l 188

5000 . r 11r ■ ।

. 44 54 । 66 । । 80 94 22.80 23.00 23.20 23.40 O-P 11 lmdt 11) 111111 r 11 rthi 11 bi 11 i11111 r 1'' I m/z 94.10 12.96% mlz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

5000 22.80 23.00 23.20 23.40 80 m/z 189.10 12.67% 94 160

m/z-> 30 42 52 66 11 102110118' 132 146 0 I | r r I I | I I I I | I ! I T j I I I l'| I I I I | I I I'l 1TTt | I I I I I 1 I I I I I I I I I I I I I I I I I I j I I I I I 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 ...179.189,... TT

Abundance #79771:3-Amino-4-methyl-6-methoxyquinoline 188

145 22.80 23.00 23.20 23.40 5000 m/z 160.10 12.00%

117 41 51 63 77 89 102 130 159 173 il O-P - I TT /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #125696: 2-Quinolinecarboxaldehyde, 8-hydroxy-, oxime ........ /....................... 1 1 I > 1 1 1 T 1 ' 1 r'| । 1 1 । I । । ' ' । 188 22.80 23.00 23.20 23.40 m/ z 184.10 9.42%

5000 143 . 89 115 , 1«W 170

m/z-> 51 64 76 | 0 11111111111111111’ 11 Ml’ । |'i i'l1,111 "+1 1111 i’i 111 III 111 I‘]‘r 11 20 30 40 50 60 70 80 90 100 110 120 130 102 । 130 all—MR TTT 140 150 160 170 180 190 22.80 23.00 23.20 23.40

10304.D 050102.M Thu May 09 13:50:25 2002 Page 15

NYC-WTC_000045111

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NYC-WTC_000045111Source: NYC Law Department, mirrored locally

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