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GCMS analysis results for sample AE10303, May 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10303 conducted on May 17, 2002.

NYC-WTC_000045075–000045091

Folder label: “GCMS X 5/1/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\10303.D Vial: 6 Acq On 8 May 2002 5:53 pm Operator: Mclean Sample 5/1 eh Inst : Instrumen Mise : Muitiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ******************************************************************** * Peak Number 5 2,4-Diamino-6-(hydroxymethy... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.30 ug/L 362150 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2,4-Diamino-6-(hydroxymethyl )pte... 192 C7H8N60 000945-24-4 59, 2 2,4-Diamino-6-(hydroxymethyl)pte.. . 192 C7H8N60 000945-24-4 59 3 Bitoscanate 192 C8H4N2S2 004044-65-9 58 4 Phenanthrene, 2-methyl-192 C15H12 002531-84-2 45 Abundance Scan 3318 (22.574 min): 10303.D (-3307) (-) m/z 192.10 100.00% 192

5000 ......................)............. 96 146 160 49 66 82 22.20 22.40 22.60 22.80 23.00 O-T TTTT TTTTTTHHT I [ I I 11 I I I I I120 [ I > I I I t I I I [ I 11 '■ i'" ''I" " i" " ।"111 m/z 146.00 15.68% z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #125821:2,4-Diamino-6-(hydroxymethyl)pteridine 43 192 163

5000 28 ...... A....... 22.20 22.40 22.60 22.80 23.00 53 68 146 175 m/z 191.10 15.05% 78 92 106 121 133 O-TT -------- HHH HL mz-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #80958: 2,4-Diamino-6-(hydroxymethyl)pteridine 163 192 43

22.20 22.40 22.60 22.80 23.00 5000 m/z 96.10 13.38%| 28 53 68 146 176 78 92 106 121 133 O-T I'"'11,1'I —pla—l++tlI triHHILTIT /z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #125827: Bitoscanate 192 22.20 22.40 22.60 22.80 23.00 m/z 193.00 13.32% 5000 134 50 63 75 90 160 102

/z-> 4 14 0 111'1" 111 “ I .281.3%/.,. „| 148 +4. 1 tH HTTr i11'' i' "11 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 200 116 ...................... ), 22.20 22.40 22.60 22.80 23.00

10303.D 050102.M Thu May 09 13:49:51 2002 Page 8

NYC-WTC_000045087

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