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GCMS blank analysis results for sample AE10901, May 2002

Machine-extracted title · confidence 95%

Laboratory report showing non-detectable levels of nitrosamines and other contaminants in a GC/MS blank sample AE10901.

NYC-WTC_000023843–000023858

Folder label: “GCMS X 5/10/02 A 5/14/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\051402\0510LB.D Vial: 3 Acq On : 14 May 2002 3:07 pm Operator: Mclean Sample : 5/10 kb Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 Phenanthrene, 9-methyl- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T. 22.58 0.27 ug/L 325698 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53 2 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N6O 000945-24-4 53 3 1,3-Benzodioxole, 4-methoxy-6-(2... 192 C11H1203 000607-91-0 40 4 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-940 Abundance Scan 3319 (22.580 min): 051 OLB.D (-3309) (-) m/z 192.10 100”. 00% 192

5000 ----- 146

n/z-> Abundance 0 42 54 70 82 i ■ ■ ■ ■ i ■ > ■ • 11" “'l111 < ['' 11 [ 1111111। j i 96 120 T" "I"''I1'"1111'I'1,1 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #81033: Phenanthrene, 9-methyl- ..r. ... j + 160 । 22.20 22.40 22.60 22.80 23.00 m/z 146.10 17.40%l

192

5000 ,1..... A 22.20 22.40 22.60 22.80 23.00 m/z 191.10 16.15%| _ 96 -|55 , , 29 39 51 63 74 83 | 115 126 139 152 । 176 0-111—00—00mm——0—1—mEmapm*tuHmg 1 ■ i" miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125821:2,4-Diamino-6-(hydroxymethyl)pteridine 43 192 163 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.10 14.91% 28 53 68 146 175 , 77 92 106 121 133

m/z-> 0- ----- 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 +— 'k". Ji-.uJl... Il TTTT

Abundance #125833:1,3-Benzodioxole, 4-methoxy-6-(2-propenyl)- ......... 1 I ‘ ' I ‘ ' 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 12.13%

5000

91 165 39 53 65 77 . 105 119 । 131 147 27 177 II " i'1 0 Tp 1 m ' 1, i llm ILI’/r rl 11 lmr । r’m ml I mr TH THTTT mmm Tdt n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

0510LB.D 050102.M Thu May 16 14:35:00 2002 Page 9

NYC-WTC_000023855

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NYC-WTC_000023855Source: NYC Law Department, mirrored locally

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