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GCMS analysis results for unknown compounds, sample AE10200, May 2002

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Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE10200 on May 10, 2002.

NYC-WTC_000044942–000044958

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\10200.D Vial: 18 Acq On 9 May 2002 5:16 am Operator: Mclean Sample 4/30 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 Anthracene-dlO- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

23.11 0.51 ug/L 624760 Phenanthranene -dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-dlO- 188 C14D10 001719-06-8 86 2 Phenanthrene-dlO 188 C14D10 001517-22-2 50 3 3,4-Oxazolidinecarboxylic acid, ... 245 C11H19NO5 116842-10-5 38 4 4-Methyl-2-(4-fluorophenyl)pyrim... 188 C11H9FN2 076128-67-1 36 Abundance Scan 3409 (23.109 min): 10200.D (-3402) (-) m/z 188.10 100.00%[ 188 A

5000 ... ..... ........... । i | I r i r | I i > । । i i i ‘lkk.h । 94 22.80 23.00 23.20 23.40 41 52 66 78 | 132 146 180 , 0 , , r> . 1—1—1—————H—i1,1" I I—[ I । I I—| I H I | H I — i r । i | "" — I | i r 1 1 i 1 1 1 1 i m/ z 94.00 14.60% m/z->_____ 20 40 60 80 _100 120 140 160 180 200 220 Abundance #79826: Anthracene-d10- 188

5000 22.80 23.00 23.20 23.40 m/ z 189.10 12.45% 80 94 160 0- 1728.40,52,54——4l104.118,132146,-170,—4, ■ 1 i ■ ■ ' 1 i ' 1 ■ ■ i

m/z-> 20 40 60 80 100 120 140 160 180 200 220 Abundance #79827: Phenanthrene-d10 188 .. 1........ 1 1 i 1 r ' 1 1 ■ ■ ' ■ i r 1 1 ■ i 1 1 ' ' i 22.80 23.00 23.20 23.40 5000 m/z 184.05 11.68%

80 94 160 1 108 120 132 146 1 170 I, 0- , . , 28 40 52 66 , I I | | IIDiII I r[IIIII 1 1 i 1 1 1 ' । 1 1 1 1 । /z-> 20 40 60 80I 100 120 140 160 180 200 220 Abundance #79684: 3,4-Oxazolidinecarboxylic acid, 2-(1,1-dimethyleth... ______ ) V i i i i_____________ UtII i r" i | f | i i | i i > [ 188 22.80 23.00 23.20 23.40 m/z 160.10 6.18% A 5000

42 88 56 144 29

m/z-> 0 1 11. ' 'I11''' 20 40 .1.79. 60 199 80 100 116 128 | 160170 , 1.... 4 214 230 ' ''''I ' 1 ' ■ । i • ■ ■ | ■ ■ ■ - । ■ ■ ' i 1 ' 100 120 140 160 180 200 220 - 22.80 23.00 23.20 23.40 1 1 i ■ ' 1 1 i

10200.D 050102.M Thu May 09 13:36:35 2002 Page 9

NYC-WTC_000044955

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