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GCMS blank analysis results for volatile organics, May 2002

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Laboratory report showing blank sample analysis results for volatile organic compounds using gas chromatography-mass spectrometry on May 9, 2002.

NYC-WTC_000044858–000044872

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\430LB.D Vial: 12 Acq On 9 May 2002 12 : 22 am Operator: Mclean Sample 4/30 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98. L

Peak Number 4 Phenanthrene-dlO Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 23.11 0.48 ug/L 781180 Phenanthranene- dl 0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-dlO 188 C14D10 001517-22-2 90 2 Anthracene-dlO- 188 C14D10 001719-06-8 90 3 5-Oxazolecarboxamide, 2-phenyl- 188 C10H8N2O2 039819-42-6 47 4 Pentacyclo[8.4.0.0(3,7).0(4,14).... 188 C14H20 1000099-27-2 36 Abundance Scan 3409 (23.109 min): 430LB.D (-3403) (-) m/z 188.15 100.00% 188 A

5000 i । j । — । - । — । । । ।—।—।—।—।—।—।—।—r 80 94 43 57 66 132 1 46 160 M 0- 1111 ' 1 -+ I''l 11111 i'i 111' H I l) I L ! | I ' ! । | > । I I | I I ! I | I । ! । | KI tri > I I'l'l I I I j I I I I | I'PI [ 1 , ! 1 | 22.80 23.00 23.20 23.40 m/z 189.20 16.13% /z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

5000 1 ' I 1 Til I I I I I I I I l t 22.80 23.00 23.20 23.40 m/ z 94.05 15.25% 80 94 160 30 42 52 66 108 118 132 146 I. 1701791,ill 0- r 11' r Tpmto rr i 1 T | I ri i | । i । । |'I । I r ] i r | "7 "‘Il’l’i I I I | i i i i | llllll|l[ i i r n n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d 10- 188

22.80 23.00 23.20 23.40 5000 m/ z 80.10 13.37%

_ 66 80 94 160 .h 17 30 42 52 P J J 108 118 132 146 ,jj 170179. 0 111"1111111111111111111111111 —mm———mmp——‘m—mmmm m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79737: 5-Oxazolecarboxamide, 2-phenyl- 1 1 J-1 I I I I ' I I I I I I I I [ I I I P

116 188 22.80 23.00 23.20 23.40 144 m/z 184.10 11.68%

5000 89

28 ।,39 51 63 77 105 . 0 4 1 " joni i'I'i 1111 rl 11 rll r- r111111111 1 ' i ■ ' f' I 1 1 ' • I > > 1 1 I m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

430LB.D 0.50102.M Thu May 09 13:30:09 2002 Page 7

NYC-WTC_000044870

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