GCMS calibration data for volatile organic compounds, April 2002

NYC 9/11 Public Portal Document

Data File C:\HPCHEM\1\DATA\APR2 5 0 2\CAL5 0.D Vial: 2 Acq On 25 Apr 2002 9:33 am Operator : Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 25 14:19 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 476593 20.00 ug/1 -0.03 10) Naphthalene-d8 15.85 136 1744375 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.15 164 1015735 20.00 ug/1 -0.02 30) Phenanthrene-diO 25.59 188 1523817 20.00 ug/1 -0.03 39) Chrysene-dl2 33.65 240 1077308 20.00 ug/1 -0.03 45) Perylene-dl2 37.88 264 710681 20.00 ug/1 -0.04

System Monitoring Compounds 28) TCMX 0.00 209 0 0.00 ug/L Spiked Amount 10.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds 2) N-nitroso-dimethyl amine 5.86 74 487529 35-05 47.00 ug/1 Qvalue 99 3) bis(2-Chloroethyl)ether 11.62 93 763521 47.29 ug/1 99 4) 1,3-Dichlorobenzene 12.11 146 830966 49.91 ug/1 100 5) 1,4-Dichlorobenzene 12.26 146 840430 50.17 ug/1 99 6) 1,2-Dichlorobenzene 12.78 146 781702 50.25 ug/1 100 7) 2,21-oxybis(1-Chloropropan 13.09 45 1019091 45.69 ug/1 99 8) N-Nitroso-di-n-propylamine 13.50 70 496214 46.87 ug/1 99 9) Hexachloroethane 13.62 117 298551 48.64 ug/1 100 11) Nitrobenzene 13.90 77 737540 48.23 ug/1 99 12) Isophorone 14.55 82 1399879 48.38 ug/1 99 13) bis(2-Chloroethoxy)methane 15.22 93 915098 48.55 ug/1 99 14) 1,2,4-Trichlorobenzene 15.74 180 695865 52.48 ug/1 99 15) Naphthalene 15.91 128 2109394 50.30 ug/1 100 16) Hexachlorobutadiene 16.44 225 356950 53.83 ug/1 98 18) Hexachlorocyclopentadiene 18.64 237 247274 55.04 ug/1 98 19) 2-Chloronaphthalene 19.41 162 1313164 49.02 ug/1 98 20) Dimethylphthalate 20.50 163 1515122 49.06 ug/1 99 21) 2,6-Dinitrotoluene 20.72 165 361962 49.02 ug/1 96 22) Acenaphthylene 20.69 152 1831415 48.87 ug/1 100 23) Acenaphthene 21.25 153 1307462 49.08 ug/1 100 24) 2,4-Dinitrotoluene 21.89 165 468674 48.22 ug/1 98 25) Diethylphthalate 22.64 149 1434381 48.42 ug/1 99 26) 4-Chlorophenyl-phenylether 22.79 204 681600 51.86 ug/1 99 27) Fluorene 22.77 166 1430291 50.70 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.26 77 1395056 44.50 ug/L 97 31) N-Nitrosodiphenylamine 23.18 168 646896 51.03 ug/1 98 32) 4-Bromophenyl-phenylether 24.26 248 392184 53.02 ug/1 94

(#) = qualifier out of range (m) = manual integration CAL50.D GCMS0412.M Thu Apr 25 14:45:45 2002 Page 1

NYC-WTC_000044767