GCMS calibration table for TCLP analysis, April 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\l\DATA\APR2502\9335.D Vial: 12 Acq On : 25 Apr 2002 11:23 pm Operator: Sample : gc/ms scan 4/18 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title 209 625/TCLP calibration table Library C : \DATABASE\NBS75K . L ********************************************************************* Peak Number 2 2-Acetylthiazole Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

8.25 0.62 ug/1 100976 1,4-Dichlorobenzene-d4 12.22

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Acetylthiazole 127 C5H5NOS 024295-03-2 4 2 N-Acetylpyrrolidone 127 C6H9NO2 000932-17-2 4 3 Octacosane 394 C28H58 000630-02-4 4 4 Dotriacontane 451 C32H66 000544-85-4 4 Abundance Scan 349 (8.249 min): 9335.D (-) m/ z 43.05 100.00% 43

5000 i > i i । i i i r । i । i P i i > [ i i - 61 OO 125

TTTT 1183,99.1 ...................... 1111 r''' !′ ir 111111111'' ■ • (■ । ।' । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ t i11111 i " 1' i ’1 8.00 m/z 124.75 8.20 8.40 8.60 17.28% m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #4717: 2-Acetylthiazole 43

5000 99 127 8.00 8.20 8.40 8.60 m/z 35.00 15.81%

m/z-> 20 40 60 44 T i । । । ii »I i । । । । 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 i ■' " i " ■' i'1 ■ ■ i ■1111 111 " ' I'11111 ‘' I''

Abundance 43 #4732: N-Acetylpyrrolidone I LI 1 1 । ■ ■ ■ ■ । 1 1 ■ 8.00 8.20 8.40 8.60 5000 m/z 60.95 14.73% 99 127

i i ■1111 r " 11'1" i" ‘I* r । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #74211: Octacosane ' 1 i 1 1 1 ■ r1 ' 1 i 1 1 ‘ ' i ' ' 1 43 8.00 8.20 8.40 8.60 m/ Z 39.95 13.97% 71 5000-

II 99 m/z-> I’’’’ I'1 TT | ll j .........155 183 127 .......................... " I " " 111 " r " ' i' " ' i 211 II I I II I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I [

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 11111 364 AAAA8.00A . 8.20WAA8.4, 0, . M8.60..A

9335.D GCMS0412.M Fri Apr 26 07:55:11 2002 Page 2

NYC-WTC_000044706