GCMS reference standard data, DEP Labs, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \HPCHEM\ 1\DATA\MAY3 002\ 12 093 . D Vial: 13 Acq On : 31 May 2002 1:52 am Operator: Morgan Sample : re-ext Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) *e* Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Glycine, N-acetyl- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 8.11 0.63 ug/1 51215 1,4-Dichlorobenzene-d4 12.06 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Glycine/ N-acetyl- 117 C4H7NO3 000543-24-8 9 2 Hexyl octyl ether 214 C14H30O 000000-00-0 8 3 N-Acetylpyrrolidone 127 C6H9NO2 000932-17-2 7 4 2-Acetylthiazole 127 C5H5NOS 024295-03-2 5 Abundance / Scan 334 (8.108 min): 12093.D (-) m/z 42.90 100.00% 4)3

5000

125 TTmmTfTT 97

nz-> TT rr i ■ । 1 ■■ i . । i i i i | 10 20 30 40 +r11. 49 ' I ‘ ‘ ‘ ‘ | ‘ 1 ‘ ( I * 1 11 I 111 11 ’1 1 11 1 50 63

60 I 70 82 .. .. II 80 90 100 19 110 120 130 m/z 7.80 8.00 42.00 8.20 8.40 19.24% Abundance #3394: Glycine, N-acetyl- 33 43

5000 ' ' ' i ' ■ ' ■ i ■ ' ’ > f * 1 1 * । * 1 1 1 I 72 7.80 8.00 8.20 8.40 15 m/z 124.95 17.80% — 99 56 — 1,1 1 । 1 1 ' 1 r 1 1 ' i +-r ■ i ■ ■ ■ ■ i ■ ■ 1 ' 1 I ■ ‘ ■ i ■ ■117 ‘ ■ i ■ ■ • ■ i1 1 miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #26415: Hexyl octyl ether 43 57 85 71 T 1 7.80 8.00 8.20 8.40 5000 m/z 126.95 16.89%

miz-> ' ■ i ■' ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i 10 20 30 40 11 i ■ 1 50 —60P70 80 .90 100103.712.. ■ ■ i 1 .. 110 120 130 Abundance #4732: N-Acetylpyrrolidone —■ ■ ■ i ■ ■ • ■ i ■ ■ ‘ ■ I 1 r 1 1 I 1 1 1 1 I 43 7.80 8.00 8.20 8.40 m/z 81.9,0 12.71% 5000 99 127 86

/z—> ml 1. 10 20 30 40 50 56

60 .

70 80 , 112 ■ i ■ > • 11 ■ > • • i ■ ■ • • i ■ • • * i > • 90 100 110 120 130 ' • । ■ ■ ■ ■ । ■ • ■ ■ । ■1 ‘' i1 ■'' i 7.80 8.00 8.20 8.40

12093.D GCMS0520.M Fri May 31 11:34:22 2002 Page 2

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