GCMS analysis results for sample AE09335, May 2002

NYC 9/11 Public Portal Document

Data File C:\MSDCHEM\1\DATA\050202\9335.D Vial : 13 Acq On 2 May 2002 9:27 pm Operator: Mclean Sample 4/29 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 10 Benzyl butyl phthalate Concentration Rank 15

R.T. EstConc Area Relative to ISTD R.T.

29.53 0.22 ug/L 302996 Chrysene-dl2 30.82

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzyl butyl phthalate 312 C19H20O4 000085-68-7 80 2 Benzyl butyl phthalate 312 C19H20O4 000085-68-7 64 3 Benzyl butyl phthalate 312 C19H20O4 000085-68-7 53 4 Phthalic acid, 2-hexyl ester________ 250 C14H1804 1000142-43-9 50 Abundance Scan 4501 (29.525 min): 9335.D (-4495) (-) m/z 149.10 100.00% 149 91

5000 40 123 206 I A | ' 1 1 1 [ ' ' ' > | 57 76 105

m/z-> '1 1 1 1 20 —4+ 40 60 80 I। । llll . l II , । i i । । । । । n I 100 120 140 160 180 200 220 240 260 280 300 I ' ‘ ''I । । । । । i }i ( r r । i i n । r trs | 1 1 1 1 I 29.20 29.40 29.60 29.80 m/z 91.10 81.30% Abundance #123465: Benzyl butyl phthalate 149 91

A_________________ 5000 i 11 ■ ■ । ■ ■ ■ ■ । 29.20 29.40 29.60 29.80 65 206 m/ z 40.10 25.88% 105 123 2711, 1. — +— I fv* TIF++ r I 1 1 1 15 I I > I [ l' I 178 I rI I I I I I I ' I I I I ' 238 I I I I I > I I I I I I I I I I I I ' < I r I

m/z--> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #66846: Benzyl butyl phthalate 149 91 i ' ' ■ 1 i 1 ■ ■ ' i 29.20 29.40 29.60 29.80 5000 m/z 206.10 23.78%

65 206 41 105 123 if 11 h 1 , .a । I 164178 238 312 1 i । । । । । । । । । rt । r । । r । । I — T I [ I I 1tgt-On | I I I I | I T I I | I I I I | I I I 1 I I I I | I

m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #123464: Benzyl butyl phthalate rr ‘"B 149 29.20 29.40 29.60 29.80 m/z 123.00 20.97%

5000 91 29 _ 57 — 226 223238 14 43 7 1.76 105 123 Til । । 1T1 । । । । 1 t । ct 1 1 । rr 178 TIIT ' I ' 1 1 1 i 1 1 1 ' i ' ■ 1 ■ i' ' 1 1 i 1 ' '' i 278 312 । । । ■ • • ■ । m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29.60 29.80

9335.D 050102.M Mon May 06 13:59:53 2002 Page 15

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