GCMS calibration data from April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAY0 102\CAL4 0.D Vial: 2 Acq On 1 May 2002 8:59 am Operator : Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 1 11:37 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 389931 40.00 ug/1 0.00 10) Naphthalene-d8 15.84 136 1455009 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.15 164 754275 40.00 ug/1 0.00 30) Phenanthrene-diO 25.58 188 1094885 40.00 ug/1 -0.01 38) Chrysene-dl2 33.65 240 774319 40.00 ug/1 -0.02 44) Perylene-dl2 37.87 264 491902 40.00 ug/1 -0.01

System Monitoring Compounds 2 8) TCMX 23.28 209 37228 10.14 ug/L -0.01 Spiked Amount 10.000 Recovery = 101.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.85 74 427946 40.14 ug/1 97 3) bis(2-Chloroethyl)ether 11.60 93 567571 41.04 ug/1 100 4) 1,3-Dichlorobenzene 12.10 146 502493 41.35 ug/1 98 5) 1,4-Dichlorobenzene 12.25 146 557342 41.97 ug/1 99 6) 1,2-Dichlorobenzene 12.77 146 476429 41.38 ug/1 99 7) 2,21-oxybis(l-Chloropropan 13.08 45 1165843 40.78 ug/1 100 8) N-Nitroso-di-n-propylamine 13.48 70 425038 41.01 ug/1 99 9) Hexachloroethane 13.62 117 204341 40.96 ug/1 97 11) Nitrobenzene 13.89 77 534565 40.34 ug/1 100 12) Isophorone 14.53 82 1053359 41.00 ug/1 100 13) bis(2-Chloroethoxy)methane 15.22 93 656971 40.29 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 402590 40.85 ug/1 99 15) Naphthalene 15.90 128 1266768 41.58 ug/1 100 16) Hexachlorobutadiene 16.45 225 186094 41.10 ug/1 100 18) Hexachlorocyclopentadiene 18.64 237 155386 40.65 ug/1 99 19) 2-Chloronaphthalene 19.40 162 686869 41.24 ug/1 100 20) Dimethylphthalate 20.50 163 880924 41.55 ug/1 100 21) 2,6-Dinitrotoluene 20.71 165 188214 40.86 ug/1 97 22) Acenaphthylene 20.67 152 1252890 41.80 ug/1 99 23) Acenaphthene 21.24 153 739085 42.03 ug/1 100 24) 2,4-Dinitrotoluene 21.88 165 205211 41.55 ug/1 96 25) Diethylphthalate 22.62 149 805845 41.90 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 389321 42.79 ug/1 99 27) Fluorene 22.76 166 801235 42.75 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 1087968 42.11 ug/L 99 31) N-Nitrosodiphenylamine 23.17 168 317500 43.74 ug/1 99 32) 4-Bromophenyl-phenylether 24.25 248 214259 40.28 ug/1 97 33) Hexachlorobenzene 24.68 284 241203 40.61 ug/1 99 34) Phenanthrene 25.66 178 1106713 41.71 ug/1 100

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS0501.M Wed May 01 11:39:54 2002 Page 1

NYC-WTC_000044257