GCMS calibration analysis CAL40, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAY0 3 0 2\CAL4 0.D Vial: 100 Acq On 4 May 2002 4:33 pm Operator: Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 7 14:21 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 488632 40.00 ug/1 -0.02 10) Naphthalene-d8 15.83 136 1785697 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.14 164 942169 40.00 ug/1 -0.01 30) Phenanthrene-diO 25.58 188 1337632 40.00 ug/1 -0.01 38) Chrysene-dl2 33.65 240 894081 40.00 ug/1 -0.02 44) Perylene-dl2 37.87 264 554853 40.00 ug/1 -0.01

System Monitoring Compounds 28) TCMX 23.27 209 47754 10.41 ug/L -0.02 Spiked Amount 10.000 Recovery = 104.10%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.83 74 524783 39.28 ug/1 99 3) bis(2-Chloroethyl)ether 11.59 93 685618 39.56 ug/1 97 4) 1,3-Dichlorobenzene 12.09 146 633808 41.62 ug/1 99 5) 1,4-Dichlorobenzene 12.24 146 696297 41.84 ug/1 100 6) 1,2-Dichlorobenzene 12.75 146 602900 41.79 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 13.07 45 1352550 37.76 ug/1 99 8) N-Nitroso-di-n-propylamine 13.46 70 495076 38.12 ug/1 99 .9) Hexachloroethane 13.61 117 249775 39.96 ug/1 94 11) Nitrobenzene 13.87 77 603679 37.12 ug/1 99 12) Isophorone 14.52 82 1236533 39.22 ug/1 98 13) bis(2-Chloroethoxy)methane 15.21 93 792542 39.61 ug/1 99 14) 1,2,4-Trichlorobenzene 15.71 180 514451 42.53 ug/1 99 15) Naphthalene 15.89 128 1569061 41.97 ug/1 99 16) Hexachlorobutadiene 16.43 225 238713 42.96 ug/1 99 18) Hexachlorocyclopentadiene 18.63 237 190325 39.86 ug/1 98 19) 2-Chloronaphthalene 19.39 162 874282 42.02 ug/1 99 20) Dimethylphthalate 20.49 163 1104950 41.72 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 215786 37.50 ug/1 95 22) Acenaphthylene 20.67 152 1568575 41.90 ug/1 100 2 3) Acenaphthene 21.23 153 934213 42.53 ug/1 100 24) 2,4-Dinitrotoluene 21.87 165 225420 36.54 ug/1 95 25) Diethylphthalate 22.62 149 994550 41.40 ug/1 100 26) 4-Chlorophenyl-phenylether 22.77 204 494591 43.52 ug/1 100 27) Fluorene 22.75 166 1004086 42.89 ug/1 100 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 1233172 38.21 ug/L 99 31) N-Nitrosodiphenylamine 23.16 168 386489 43.58 ug/1 98 32) 4-Bromophenyl-phenylether 24.24 248 273898 42.15 ug/1 98 3 3) Hexachlorobenzene 24.67 284 313311 43.17 ug/1 100 34) Phenanthrene 25.65 178 1363470 42.06 ug/1 100

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS0501.M Tue May 07 14:24:55 2002 Page 1

NYC-WTC_000023014