GCMS analysis results, sample AE09972, May 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\050602\9972 .D Vial: 20 Acq On : 7 May 2002 3:11 am Operator: Mclean Sample : 4/25 Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L Peak Number 14 1,3-Cyclopentadiene, 5-(tra... Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T. 34.90 0.21 ug/L 166298 Perylene-dl2 34.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,3-Cyclopentadiene, 5-(trans-2-... 146 C11H14 1000139-17-5 25 2 1,2,4-Metheno-IH-cyclobuta[cd]pe... 160 C10H8O2 014725-77-0 9 3 3-p-Tolylprop-2-enal 146 C10H10O 1000202-14-8 9 4 Cinnamyl cinnamate 264 C18H1602 000122-69-0 9 Abundance Scan 5416 (34.901 min): 9972.D (-5414) (-) m/z 131.50 100.00% 131

5000 73 116 36 51 264 281 208 1/1’1*’1115*/+/1*/*//’/I’/’/III 34.60 34.80 35.00 35.20 TTt I I ' 1 ' ' I ' 1 1 1 I ■ ' 1 1 1 1 + ... 11111111 - 111111111111111111 L 1 1 1 ' 1 m/z 116.00 42.28% m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #59166:1,3-Cyclopentadiene, 5-(trans-2-ethyl-3-methylcycl... 131 91

) 5000 115 1 ' I ' ' •I 1 1 1 ' I 1 1 1 1 I 34.60 34.80 35.00 35.20 77 103 146 m/ z 73.10 41.46%

ti/z-> Tl.T 20 39I. 51 63 Ji ll 1 I 1 1 1 1 1 ' 40 60 4 I ' 1 1 1 I '' I > I I 1 I > I I >> I I I I I I [ I I I < I I I 80 100 120 140 160 180 200 220 240 260 1 1 i ' ‘ 1 1 i ‘ ' 280 jl M Abundance #59259:1,2,4-Metheno-1 H-cyclobuta[cd]pentalene-3,5-dione,... 131 IL 104 17 i ‘ '

78 34.60 34.80 35.00 35.20 5000 m/ Z 115.00 37.20% 51 160 26 39 ° I ll 63 Il , ,1 , 1,1, al, 91 118 148 , TUiB i i i । i ili | 7 । 1 TT—TT । । ■ n i । i r i—i । i i n 1 । i । । i n । । । m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 ) ________________ Abundance #59181:3-p-Tolylprop-2-enal ' ’ । i r > r । I । । । । > > ' । । । ' । । । 111 34.60 34.80 35.00 35.20 m/ z 117.10 36.79% 5000 91 115 146 39 65 103 II 51 77 .. i. A 4 m/z-> .... 20 40 r 60 80 100 120 ■i11'1।11■1i1111।■1 ' 1 । 1 1 1 ’ i ■ ■ ' ' i ■ ■ ■ 1 i ■ ' ' 1 i ■ ■ 1 ’I ■'"I 1 ' ' ' I 140 160 180 200 220 240 260 280 34.60 34.80 35.00 35.20

9972.D 050102.M Tue May 07 15:51:03 2002 Page 18

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