GC/MS calibration table, sample AE08837, April 2002

NYC 9/11 Public Portal Document LlDrarY searcr compound Keport

Data File : C:\HPCHEM\1\DATA\APR2 302\8837.D Vial: 6 Acq On : 23 Apr 2002 7:18 pm Operator: Sample : gc/ms scan 4/15 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Methyl tert-butyl disulphide Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 6.28 5.83 ug/1 835865 1,4-Dichlorobenzene-d4 12.22

Hit# of 5 Tentative ID MW MolForm CAS# Qual ---------------------------------------- /--------------------------------------------- 1 Methyl tert-bq'tyl disulphide 136 C5H12S2 035166-82-6 4 2 2-Acetyl-3-methylpyrazine 136 C7H8N2O 023787-80-6 4 3 3,5-Nonadien-7-yn-2-ol , (E,E)- 136 C9H120 043142-43-4 3 4 3,8-Nonadien/2-one, (E)-_________ 138 C9H140 055282-90-1 3 Abundance 7 Scan 135 (6.285 min): 8837. D (-) m/ z 42.95 100.00% V 5000

____________ ______________ i i ~i [ r i i i | > I i i । i i I t | i i i I

93 136 6.00 6.20 6.40 6.60 37. I 1,53. 79,85 | | 100 107 123 । ■ ■ ■ ■ । । ■ ■ । । i 1 ■' ।'r' ■ ।1 1 TImndLpBROIDT 1 1i■■ ■ ' I1 1 ' 1 i - m/z 42.05 14.21% mfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #6400: Methyl tert-butyl disulphide 23 57

5000 6.00 6.20 6.40 6.60 m/z 92.90 8.47% 42

m/z-> 1′7 20 .30I.40 +4850.. ,60. 64 7073 J80 94 >’i ■ 1 r > I ■ ■ ' ■ | ■ ■ ■ ■ । ■ 1 ■ । I । ' 1 > I ‘

90 100 110 > I ■ 1" |i । I । । । । ।

120 130 140 Abundance #6435: 2-Acetyl-3-methylpyrazine 43 93 136 * 1 1 I ' 1 11 [ 11 1 1 I 1 1 1 I I 1 1 ' ' 6.00 6.20 6.40 6.60 5000 m/z 135.95 8.26% 67 52 108 , i i । i i 1 | i i i i । । i ! i । r T-T-T-t 1 I [ m I I 1 I I . I 121 I I I I I I r I J_____ i ’ ■ 1 1 i 1 1 r ■ i 'I ' 1 m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #6539: 3,5-Nonadien-7-yn-2-ol, (E,E)- ■ * । | । i r i | i i i i | I I I I T Illi 43 6.00 6.20 6.40 6.60 m/z 137.95 8.14% 77 91 5000 121 65 136 51 ................. | Ii ■ 1 1 i 1 • ■ । ■ ■ > ■ । ■ J- • ■ ■ । ।। । . - i ■ 1 1 1 i 1 ■ ■ ■ i ' 1 1 1 i 11 1 1 1 ■ 1 1 ' I ' n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 6.00 6.20 6.40 6.60

8837.D GCMS0412.M Wed Apr 24 08:36:34 2002 Page 1

NYC-WTC_000043705