GC/MS calibration table, sample AE08837, April 2002

NYC 9/11 Public Portal Document LLDLaLy sedICI compounu Keport

Data File : C:\HPCHEM\1\DATA\APR2302\8837.D Vial: 6 Acq On : 23 Apr 2002 7:18 pm Operator: Sample : gc/ms scan 4/15 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title 209 625/TCLP calibration table Library C: \DATABASE\NBS75K. L Peak Number 2 2-Methyl-4-bromo-l-butene Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T. 6.55 0.68 ug/1 97566 1,4-Dichlorobenzene-d4 12.22

Hit# of 5 ,Tentative ID MW MolForm CAS# Qual 1 2-Methyl-4/bromo-l-butene 148 C5H9Br 020038-12-4 74 2 Meparfynol 98 C6H10O 000077-75-8 53 3 1 -Butene,/ 3,3-dimethyl- 84 C6H12 000558-37-2 43 4 1,5-Heptadiene, 3,6-dimethyl-_____ 124 C9H16 034891-10-6 40 Abundance 7 Scan 164 (6.551 min): 8837. D (-) m/ z 69.00 100.00% 41 69

5000 ............... _............... _........... , I i 1 i i i | i i i i । i i i i j l i i—[—r 53 620 6.40 6.60 6.80

m/z-> - — 82 .................................. —HH TTT 136 148 1 1 I I I I I I I I I >1 I I I I I I I I f I 1 I I I I I I I

10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 i1 ‘1 1 r 1 1 1 i I t I I > I I I I I ] I I I I m/z 41.00 89.98% Abundance #9146: 2-Methyl-4-bromo-1 -butene 69

41 5000 1 'i 1 1 1 1 । 1 1 ' 1 । 1 T1 620 6.40 6.60 6.80 55 m/ Z 39.05 20.46% 27 148 fl ............... 1,,, TTI’ 11 ' I ' 1 11 1 1 THT ■ i111 ‘ i1 —4 | । । ' । । ' > < । । < < । < । । । । । । । । (”r11 ’i i i11 | i i i I | i I I I | i r i r

mfe-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Abundance #1293: Meparfynol 69 I I v i । i ] 1 । i [ i P T । "M Am 620 6.40 6.60 6.80______ 43 m/z 53.00 12.85% 5000

27 83 15 53

m/z-> Iapol P . . 11 , 10 20 30 40 50 60 TT 1 r 1 r ■ i11'r i 97 i 1 1 1 11 70 80 90 100 110 120 130 140 150 I I I I I I I I I I I I I

Abundance #587:1-Butene, 3,3-dimethyl- AM............. I ' 1 ■ • । ' । ' । । । । । । । । 41 69 620 6.40 6.60 6.80 m/ z 66.95 8.06%

5000 27 15 84 53 ....... | ...................... .li.l, r 1 r '1 1 i 1 — 1|IIIIplIII|fIIIITT TTr ' ' I 1 i r | । i ' । | I-1 i । | i i r i ill ITTuu I I | I I' 1' I | I I TIT m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 6.20 6.40 6.60 6.80

8837.D GCMS0412.M Wed Apr 24 08:36:35 2002 Page 2

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